Investigating the evolving microstructure of lithium metal electrodes in 3D using X-ray computed tomography
(2017) In Physical Chemistry Chemical Physics 19(33). p.22111-22120- Abstract
The growth of electrodeposited lithium microstructures on metallic lithium electrodes has prevented their use in rechargeable lithium batteries due to early performance degradation and safety implications. Understanding the evolution of lithium microstructures during battery operation is crucial for the development of an effective and safe rechargeable lithium-metal battery. This study employs both synchrotron and laboratory X-ray computed tomography to investigate the morphological evolution of the surface of metallic lithium electrodes during a single cell discharge and over numerous cycles, respectively. The formation of surface pits and the growth of mossy lithium deposits through the separator layer are characterised in... (More)
The growth of electrodeposited lithium microstructures on metallic lithium electrodes has prevented their use in rechargeable lithium batteries due to early performance degradation and safety implications. Understanding the evolution of lithium microstructures during battery operation is crucial for the development of an effective and safe rechargeable lithium-metal battery. This study employs both synchrotron and laboratory X-ray computed tomography to investigate the morphological evolution of the surface of metallic lithium electrodes during a single cell discharge and over numerous cycles, respectively. The formation of surface pits and the growth of mossy lithium deposits through the separator layer are characterised in three-dimensions. This has provided insight into the microstructural evolution of lithium-metal electrodes during rechargeable battery operation, and further understanding of the importance of separator architecture in mitigating lithium dendrite growth.
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- author
- Taiwo, Oluwadamilola O. ; Finegan, Donal P ; Paz-Garcia, J. M. LU ; Eastwood, David S. ; Bodey, A. J. ; Rau, Donald C. ; Hall, S. A. LU ; Brett, Dan J. L. ; Lee, Peter D. and Shearing, Paul R.
- organization
- publishing date
- 2017
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Chemistry Chemical Physics
- volume
- 19
- issue
- 33
- pages
- 10 pages
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:85028550062
- pmid:28795708
- wos:000408257700022
- ISSN
- 1463-9076
- DOI
- 10.1039/c7cp02872e
- language
- English
- LU publication?
- yes
- id
- 478e35ac-b4f2-4d8f-9186-4393c0d77baa
- date added to LUP
- 2017-09-28 09:06:28
- date last changed
- 2024-12-09 19:23:48
@article{478e35ac-b4f2-4d8f-9186-4393c0d77baa,
abstract = {{<p>The growth of electrodeposited lithium microstructures on metallic lithium electrodes has prevented their use in rechargeable lithium batteries due to early performance degradation and safety implications. Understanding the evolution of lithium microstructures during battery operation is crucial for the development of an effective and safe rechargeable lithium-metal battery. This study employs both synchrotron and laboratory X-ray computed tomography to investigate the morphological evolution of the surface of metallic lithium electrodes during a single cell discharge and over numerous cycles, respectively. The formation of surface pits and the growth of mossy lithium deposits through the separator layer are characterised in three-dimensions. This has provided insight into the microstructural evolution of lithium-metal electrodes during rechargeable battery operation, and further understanding of the importance of separator architecture in mitigating lithium dendrite growth.</p>}},
author = {{Taiwo, Oluwadamilola O. and Finegan, Donal P and Paz-Garcia, J. M. and Eastwood, David S. and Bodey, A. J. and Rau, Donald C. and Hall, S. A. and Brett, Dan J. L. and Lee, Peter D. and Shearing, Paul R.}},
issn = {{1463-9076}},
language = {{eng}},
number = {{33}},
pages = {{22111--22120}},
publisher = {{Royal Society of Chemistry}},
series = {{Physical Chemistry Chemical Physics}},
title = {{Investigating the evolving microstructure of lithium metal electrodes in 3D using X-ray computed tomography}},
url = {{http://dx.doi.org/10.1039/c7cp02872e}},
doi = {{10.1039/c7cp02872e}},
volume = {{19}},
year = {{2017}},
}