Preparation and characterization of uniform molecularly imprinted polymer beads for separation of triazine herbicides
Ara, Behisht ; Chen, Zhiyong LU ; Shah, Jasmin ; Jan, M. Rasul and Ye, Lei LU
(2012)
In Journal of Applied Polymer Science
126(1).
p.315-321
- Abstract
- Uniform molecularly imprinted polymer beads were synthesized by precipitation polymerization for separation of triazine herbicides. A series of imprinted polymers were prepared using ametryn as template and divinylbenzene as crosslinking monomer, in combination with three different functional monomers under different solvent conditions. Under optimized reaction conditions, we obtained uniform molecularly imprinted polymer microspheres that display favorable molecular binding selectivity for triazine herbicides. The imprinted polymer beads synthesized using methacrylic acid as functional monomer in a mixture of methyl ethyl ketone and heptane showed the best results in terms of particle size distribution and molecular selectivity. Compared... (More)
- Uniform molecularly imprinted polymer beads were synthesized by precipitation polymerization for separation of triazine herbicides. A series of imprinted polymers were prepared using ametryn as template and divinylbenzene as crosslinking monomer, in combination with three different functional monomers under different solvent conditions. Under optimized reaction conditions, we obtained uniform molecularly imprinted polymer microspheres that display favorable molecular binding selectivity for triazine herbicides. The imprinted polymer beads synthesized using methacrylic acid as functional monomer in a mixture of methyl ethyl ketone and heptane showed the best results in terms of particle size distribution and molecular selectivity. Compared with nonimprinted polymer microspheres, the imprinted microspheres displayed significantly higher binding for a group of triazine herbicides including atrazine, simazine, propazine, ametryn, prometryn, and terbutryn. For the first time, precipitation polymerization has been used to produce highly uniform imprinted microspheres suitable for affinity separation of triazine herbicides. (C) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012 (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/2991532
- author
- Ara, Behisht
; Chen, Zhiyong
LU
; Shah, Jasmin
; Jan, M. Rasul
and Ye, Lei
LU
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- molecular imprinting, precipitation polymerization, triazine, ametryn, microspheres
- in
- Journal of Applied Polymer Science
- volume
- 126
- issue
- 1
- pages
- 315 - 321
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- wos:000306219800038
- scopus:84863854079
- ISSN
- 1097-4628
- DOI
- 10.1002/app.36882
- language
- English
- LU publication?
- yes
- id
- 479ac4c8-77c5-4081-8dde-a0365eb1f719 (old id 2991532)
- date added to LUP
- 2016-04-01 11:15:32
- date last changed
- 2022-01-26 06:35:37
@article{479ac4c8-77c5-4081-8dde-a0365eb1f719,
abstract = {{Uniform molecularly imprinted polymer beads were synthesized by precipitation polymerization for separation of triazine herbicides. A series of imprinted polymers were prepared using ametryn as template and divinylbenzene as crosslinking monomer, in combination with three different functional monomers under different solvent conditions. Under optimized reaction conditions, we obtained uniform molecularly imprinted polymer microspheres that display favorable molecular binding selectivity for triazine herbicides. The imprinted polymer beads synthesized using methacrylic acid as functional monomer in a mixture of methyl ethyl ketone and heptane showed the best results in terms of particle size distribution and molecular selectivity. Compared with nonimprinted polymer microspheres, the imprinted microspheres displayed significantly higher binding for a group of triazine herbicides including atrazine, simazine, propazine, ametryn, prometryn, and terbutryn. For the first time, precipitation polymerization has been used to produce highly uniform imprinted microspheres suitable for affinity separation of triazine herbicides. (C) 2012 Wiley Periodicals, Inc. J Appl Polym Sci, 2012}},
author = {{Ara, Behisht and Chen, Zhiyong and Shah, Jasmin and Jan, M. Rasul and Ye, Lei}},
issn = {{1097-4628}},
keywords = {{molecular imprinting; precipitation polymerization; triazine; ametryn; microspheres}},
language = {{eng}},
number = {{1}},
pages = {{315--321}},
publisher = {{John Wiley & Sons Inc.}},
series = {{Journal of Applied Polymer Science}},
title = {{Preparation and characterization of uniform molecularly imprinted polymer beads for separation of triazine herbicides}},
url = {{http://dx.doi.org/10.1002/app.36882}},
doi = {{10.1002/app.36882}},
volume = {{126}},
year = {{2012}},
}