Water dimer in solid neon. Far-infrared spectrum
(2004) In The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory 108(31). p.6499-6502- Abstract
- Infrared spectra of water and deuterated water isolated in neon matrices have been recorded between 20 and 5000 cm(-1). The water concentration has been varied between very low concentrations with only monomers present up to concentrations where pentamers and possibly hexamers are present in significant amounts. The concentration dependencies of the observed absorption bands have been used to assign the dimer spectrum. The matrices studied were on the order of 1 mm thick, which has made it simpler to vary concentrations in a manner which discriminates between higher aggregates. It has also made it possible to avoid the baseline problems which appear when the matrices are only slightly thicker than the wavelengths in the far-infrared part... (More)
- Infrared spectra of water and deuterated water isolated in neon matrices have been recorded between 20 and 5000 cm(-1). The water concentration has been varied between very low concentrations with only monomers present up to concentrations where pentamers and possibly hexamers are present in significant amounts. The concentration dependencies of the observed absorption bands have been used to assign the dimer spectrum. The matrices studied were on the order of 1 mm thick, which has made it simpler to vary concentrations in a manner which discriminates between higher aggregates. It has also made it possible to avoid the baseline problems which appear when the matrices are only slightly thicker than the wavelengths in the far-infrared part of the spectrum. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/138971
- author
- Ceponkus, Justinas and Nelander, Bengt LU
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
- volume
- 108
- issue
- 31
- pages
- 6499 - 6502
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000223002300007
- scopus:4143056838
- ISSN
- 1520-5215
- DOI
- 10.1021/jp049288v
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 4d2ffad4-4cc2-4367-b08c-637a5bfed570 (old id 138971)
- date added to LUP
- 2016-04-01 15:44:07
- date last changed
- 2022-03-22 05:55:25
@article{4d2ffad4-4cc2-4367-b08c-637a5bfed570,
abstract = {{Infrared spectra of water and deuterated water isolated in neon matrices have been recorded between 20 and 5000 cm(-1). The water concentration has been varied between very low concentrations with only monomers present up to concentrations where pentamers and possibly hexamers are present in significant amounts. The concentration dependencies of the observed absorption bands have been used to assign the dimer spectrum. The matrices studied were on the order of 1 mm thick, which has made it simpler to vary concentrations in a manner which discriminates between higher aggregates. It has also made it possible to avoid the baseline problems which appear when the matrices are only slightly thicker than the wavelengths in the far-infrared part of the spectrum.}},
author = {{Ceponkus, Justinas and Nelander, Bengt}},
issn = {{1520-5215}},
language = {{eng}},
number = {{31}},
pages = {{6499--6502}},
publisher = {{The American Chemical Society (ACS)}},
series = {{The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory}},
title = {{Water dimer in solid neon. Far-infrared spectrum}},
url = {{http://dx.doi.org/10.1021/jp049288v}},
doi = {{10.1021/jp049288v}},
volume = {{108}},
year = {{2004}},
}