Insertion of carbon dioxide into (PCP)Pd-II-Me bonds
(2005) In Organometallics 24(19). p.4500-4502- Abstract
- A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/151835
- author
- Johansson, Roger LU ; Jarenmark, Martin LU and Wendt, Ola LU
- organization
- publishing date
- 2005
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Organometallics
- volume
- 24
- issue
- 19
- pages
- 4500 - 4502
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- wos:000231784200002
- scopus:25444468604
- ISSN
- 1520-6041
- DOI
- 10.1021/om0505561
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Department of Chemistry (011001220)
- id
- 4fc81e3d-cc0d-4bc0-bab9-177cf52ef46f (old id 151835)
- date added to LUP
- 2016-04-01 12:04:01
- date last changed
- 2022-03-20 23:01:05
@article{4fc81e3d-cc0d-4bc0-bab9-177cf52ef46f, abstract = {{A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.}}, author = {{Johansson, Roger and Jarenmark, Martin and Wendt, Ola}}, issn = {{1520-6041}}, language = {{eng}}, number = {{19}}, pages = {{4500--4502}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Organometallics}}, title = {{Insertion of carbon dioxide into (PCP)Pd-II-Me bonds}}, url = {{http://dx.doi.org/10.1021/om0505561}}, doi = {{10.1021/om0505561}}, volume = {{24}}, year = {{2005}}, }