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Microporous La-Metal-Organic Framework (MOF) with Large Surface Area

Pal, Souvik; Bhunia, Asamanjoy; Jana, Partha LU ; Dey, Subarna; Moellmer, Jens; Janiak, Christoph and Nayek, Hari Pada (2015) In Chemistry: A European Journal 21(7). p.2789-2792
Abstract
A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
adsorption, chemical stability, lanthanides, metal-organic frameworks, structure elucidation
in
Chemistry: A European Journal
volume
21
issue
7
pages
2789 - 2792
publisher
John Wiley & Sons
external identifiers
  • wos:000349384300011
  • scopus:84921939630
ISSN
1521-3765
DOI
10.1002/chem.201405168
language
English
LU publication?
yes
id
11827172-b70f-4c03-8769-0585c5916225 (old id 5175894)
date added to LUP
2015-03-25 12:39:16
date last changed
2017-11-12 03:46:03
@article{11827172-b70f-4c03-8769-0585c5916225,
  abstract     = {A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.},
  author       = {Pal, Souvik and Bhunia, Asamanjoy and Jana, Partha and Dey, Subarna and Moellmer, Jens and Janiak, Christoph and Nayek, Hari Pada},
  issn         = {1521-3765},
  keyword      = {adsorption,chemical stability,lanthanides,metal-organic frameworks,structure elucidation},
  language     = {eng},
  number       = {7},
  pages        = {2789--2792},
  publisher    = {John Wiley & Sons},
  series       = {Chemistry: A European Journal},
  title        = {Microporous La-Metal-Organic Framework (MOF) with Large Surface Area},
  url          = {http://dx.doi.org/10.1002/chem.201405168},
  volume       = {21},
  year         = {2015},
}