Microporous La-Metal-Organic Framework (MOF) with Large Surface Area
(2015) In Chemistry: A European Journal 21(7). p.2789-2792- Abstract
- A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/5175894
- author
- Pal, Souvik ; Bhunia, Asamanjoy ; Jana, Partha LU ; Dey, Subarna ; Moellmer, Jens ; Janiak, Christoph and Nayek, Hari Pada
- organization
- publishing date
- 2015
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- adsorption, chemical stability, lanthanides, metal-organic frameworks, structure elucidation
- in
- Chemistry: A European Journal
- volume
- 21
- issue
- 7
- pages
- 2789 - 2792
- publisher
- Wiley-Blackwell
- external identifiers
-
- wos:000349384300011
- pmid:25521611
- scopus:84921939630
- ISSN
- 1521-3765
- DOI
- 10.1002/chem.201405168
- language
- English
- LU publication?
- yes
- id
- 11827172-b70f-4c03-8769-0585c5916225 (old id 5175894)
- date added to LUP
- 2016-04-01 14:31:42
- date last changed
- 2022-08-07 06:00:47
@article{11827172-b70f-4c03-8769-0585c5916225, abstract = {{A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.}}, author = {{Pal, Souvik and Bhunia, Asamanjoy and Jana, Partha and Dey, Subarna and Moellmer, Jens and Janiak, Christoph and Nayek, Hari Pada}}, issn = {{1521-3765}}, keywords = {{adsorption; chemical stability; lanthanides; metal-organic frameworks; structure elucidation}}, language = {{eng}}, number = {{7}}, pages = {{2789--2792}}, publisher = {{Wiley-Blackwell}}, series = {{Chemistry: A European Journal}}, title = {{Microporous La-Metal-Organic Framework (MOF) with Large Surface Area}}, url = {{http://dx.doi.org/10.1002/chem.201405168}}, doi = {{10.1002/chem.201405168}}, volume = {{21}}, year = {{2015}}, }