Polydispersity of the photoluminescence quantum yield in single conjugated polymer chains
Mirzov, Oleg LU
and Scheblykin, Ivan
LU
(2005)
In Chemical Physics
318(3).
p.217-222
- Abstract
- The conjugated polymer poly(2-methoxy-5-(2'-ethylhexyloxy)-1,4-pheiiylene vinylene) (MEH-PPV) was studied by a single-molecule imaging technique. A comparison of statistical distributions of fluorescence intensity with molecular weight distributions revealed that the distribution of the photoluminescence quantum yield of the single polymer chains under study is significantly asymmetric, with a polydispersity greater than or similar to 2. The result implies that there are molecules whose quantum yield is a few times higher than the ensemble quantum yield. This conclusion Suggests a possibility of a great improvement of the photoluminescence quantum yield of MEH-PPV, which is known to be several times less than 1. (c) 2005 Elsevier B.V.. All... (More)
- The conjugated polymer poly(2-methoxy-5-(2'-ethylhexyloxy)-1,4-pheiiylene vinylene) (MEH-PPV) was studied by a single-molecule imaging technique. A comparison of statistical distributions of fluorescence intensity with molecular weight distributions revealed that the distribution of the photoluminescence quantum yield of the single polymer chains under study is significantly asymmetric, with a polydispersity greater than or similar to 2. The result implies that there are molecules whose quantum yield is a few times higher than the ensemble quantum yield. This conclusion Suggests a possibility of a great improvement of the photoluminescence quantum yield of MEH-PPV, which is known to be several times less than 1. (c) 2005 Elsevier B.V.. All rights reserved. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/151802
- author
- Mirzov, Oleg
LU
and Scheblykin, Ivan
LU
- organization
- publishing date
- 2005
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Physics
- volume
- 318
- issue
- 3
- pages
- 217 - 222
- publisher
- Elsevier
- external identifiers
-
- wos:000233709300006
- scopus:27844507535
- ISSN
- 0301-0104
- DOI
- 10.1016/j.chemphys.2005.06.017
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- 53131518-03f1-4c5e-b792-76fec1ab6983 (old id 151802)
- date added to LUP
- 2016-04-01 16:52:19
- date last changed
- 2024-01-11 16:28:08
@article{53131518-03f1-4c5e-b792-76fec1ab6983,
abstract = {{The conjugated polymer poly(2-methoxy-5-(2'-ethylhexyloxy)-1,4-pheiiylene vinylene) (MEH-PPV) was studied by a single-molecule imaging technique. A comparison of statistical distributions of fluorescence intensity with molecular weight distributions revealed that the distribution of the photoluminescence quantum yield of the single polymer chains under study is significantly asymmetric, with a polydispersity greater than or similar to 2. The result implies that there are molecules whose quantum yield is a few times higher than the ensemble quantum yield. This conclusion Suggests a possibility of a great improvement of the photoluminescence quantum yield of MEH-PPV, which is known to be several times less than 1. (c) 2005 Elsevier B.V.. All rights reserved.}},
author = {{Mirzov, Oleg and Scheblykin, Ivan}},
issn = {{0301-0104}},
language = {{eng}},
number = {{3}},
pages = {{217--222}},
publisher = {{Elsevier}},
series = {{Chemical Physics}},
title = {{Polydispersity of the photoluminescence quantum yield in single conjugated polymer chains}},
url = {{http://dx.doi.org/10.1016/j.chemphys.2005.06.017}},
doi = {{10.1016/j.chemphys.2005.06.017}},
volume = {{318}},
year = {{2005}},
}