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Interface instabilities of growing hydrides

Ståhle, Per LU and Reheman, Wureguli LU (2016) 21st European Conference on Fracture, ECF 2016 In Procedia Structural Integrity 2. p.589-596
Abstract
Formation of metal hydrides is a serious complication that occur when hydride forming metals such as zirconium, niobium, vanadium and magnesium are exposed to long term hydrogen environment. The main concern is that the hydride, as being a brittle material, has very poor fracture mechanical properties. Formation of hydride is associated with transportation of hydrogen along the gradients of increasing hydrostatic stress, which leads to crack tips and other stress concentrators, where it forms the hydride. In the present study the thermodynamics of the evolving hydrides is studied. The process is driven by the release of free strain, chemical, and gradient energies. A phase field model is used to capture the driving forces that the release... (More)
Formation of metal hydrides is a serious complication that occur when hydride forming metals such as zirconium, niobium, vanadium and magnesium are exposed to long term hydrogen environment. The main concern is that the hydride, as being a brittle material, has very poor fracture mechanical properties. Formation of hydride is associated with transportation of hydrogen along the gradients of increasing hydrostatic stress, which leads to crack tips and other stress concentrators, where it forms the hydride. In the present study the thermodynamics of the evolving hydrides is studied. The process is driven by the release of free strain, chemical, and gradient energies. A phase field model is used to capture the driving forces that the release of the free energy causes. The study gives the conditions that lead to hydride advancement versus retreat and under which conditions the metal-hydride interface becomes unstable and develops a waviness. The spatial frequency spectrum leading to instability is found to depend on the ratio of the elastic strain energy density and parameters related to the interface energy. (Less)
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author
and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Interface, instability, hydrides, Precipitate growth
in
Procedia Structural Integrity
volume
2
pages
7 pages
publisher
Elsevier
conference name
21st European Conference on Fracture, ECF 2016
conference location
Catania, Italy
conference dates
2016-06-20 - 2016-06-24
external identifiers
  • scopus:85055972017
ISSN
2452-3216
DOI
10.1016/j.prostr.2016.06.076
language
Swedish
LU publication?
yes
id
532eb929-a50f-49c0-863b-735cfc2f570c
date added to LUP
2019-06-04 10:14:48
date last changed
2024-04-16 09:58:59
@article{532eb929-a50f-49c0-863b-735cfc2f570c,
  abstract     = {{Formation of metal hydrides is a serious complication that occur when hydride forming metals such as zirconium, niobium, vanadium and magnesium are exposed to long term hydrogen environment. The main concern is that the hydride, as being a brittle material, has very poor fracture mechanical properties. Formation of hydride is associated with transportation of hydrogen along the gradients of increasing hydrostatic stress, which leads to crack tips and other stress concentrators, where it forms the hydride. In the present study the thermodynamics of the evolving hydrides is studied. The process is driven by the release of free strain, chemical, and gradient energies. A phase field model is used to capture the driving forces that the release of the free energy causes. The study gives the conditions that lead to hydride advancement versus retreat and under which conditions the metal-hydride interface becomes unstable and develops a waviness. The spatial frequency spectrum leading to instability is found to depend on the ratio of the elastic strain energy density and parameters related to the interface energy.}},
  author       = {{Ståhle, Per and Reheman, Wureguli}},
  issn         = {{2452-3216}},
  keywords     = {{Interface; instability; hydrides; Precipitate growth}},
  language     = {{swe}},
  month        = {{12}},
  pages        = {{589--596}},
  publisher    = {{Elsevier}},
  series       = {{Procedia Structural Integrity}},
  title        = {{Interface instabilities of growing hydrides}},
  url          = {{http://dx.doi.org/10.1016/j.prostr.2016.06.076}},
  doi          = {{10.1016/j.prostr.2016.06.076}},
  volume       = {{2}},
  year         = {{2016}},
}