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Solvation at nanoscale: Alkali-halides in water clusters

Partanen, Leena ; Mikkela, Mikko-Heikki ; Huttula, Marko ; Tchaplyguine, Maxim LU ; Zhang, Chaofan ; Andersson, Tomas and Bjorneholm, Olle (2013) In Journal of Chemical Physics 138(4).
Abstract
The solvation of alkali-halides in water clusters at nanoscale is studied by photoelectron spectroscopy using synchrotron radiation. The Na 2p, K 3p, Cl 2p, Br 3d, and I 4d core level binding energies have been measured for salt-containing water clusters. The results have been compared to those of alkali halide clusters and the dilute aqueous salt solutions. It is found that the alkali halides dissolve in small water clusters as ions. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4775586]
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author
; ; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of Chemical Physics
volume
138
issue
4
article number
044301
publisher
American Institute of Physics (AIP)
external identifiers
  • wos:000314725900018
  • scopus:84873584486
  • pmid:23387578
ISSN
0021-9606
DOI
10.1063/1.4775586
language
English
LU publication?
yes
id
55171da3-68eb-442b-8844-54bebb7490ba (old id 3580933)
date added to LUP
2016-04-01 09:54:33
date last changed
2022-01-25 17:52:48
@article{55171da3-68eb-442b-8844-54bebb7490ba,
  abstract     = {{The solvation of alkali-halides in water clusters at nanoscale is studied by photoelectron spectroscopy using synchrotron radiation. The Na 2p, K 3p, Cl 2p, Br 3d, and I 4d core level binding energies have been measured for salt-containing water clusters. The results have been compared to those of alkali halide clusters and the dilute aqueous salt solutions. It is found that the alkali halides dissolve in small water clusters as ions. (C) 2013 American Institute of Physics. [http://dx.doi.org/10.1063/1.4775586]}},
  author       = {{Partanen, Leena and Mikkela, Mikko-Heikki and Huttula, Marko and Tchaplyguine, Maxim and Zhang, Chaofan and Andersson, Tomas and Bjorneholm, Olle}},
  issn         = {{0021-9606}},
  language     = {{eng}},
  number       = {{4}},
  publisher    = {{American Institute of Physics (AIP)}},
  series       = {{Journal of Chemical Physics}},
  title        = {{Solvation at nanoscale: Alkali-halides in water clusters}},
  url          = {{http://dx.doi.org/10.1063/1.4775586}},
  doi          = {{10.1063/1.4775586}},
  volume       = {{138}},
  year         = {{2013}},
}