Dynamics of hydrogen loss and structural changes in pyrolyzing biomass utilizing neutron imaging
(2021) In Carbon 176. p.511-529- Abstract
We present results from neutron-imaging studies of slow, vacuum pyrolysis of beech, poplar and conifer wood, and pelletized biomass from room temperature up to 1000 °C. A detailed and quantitative method to extract 2D (in situ neutron radiography, NR) and 3D (ex situ neutron computed tomography, NCT) information on structural transformation and elemental hydrogen content has been developed. NCT and X-ray tomography (XCT) experiments on a carbonized beech twig permitted comparison of the spatial distribution of hydrogen, better sensed by NCT, and carbon, oxygen, and heavier elements, better sensed by XCT. We have developed a methodology to directly compare structure and hydrogen-loss dynamics measured using neutron imaging with... (More)
We present results from neutron-imaging studies of slow, vacuum pyrolysis of beech, poplar and conifer wood, and pelletized biomass from room temperature up to 1000 °C. A detailed and quantitative method to extract 2D (in situ neutron radiography, NR) and 3D (ex situ neutron computed tomography, NCT) information on structural transformation and elemental hydrogen content has been developed. NCT and X-ray tomography (XCT) experiments on a carbonized beech twig permitted comparison of the spatial distribution of hydrogen, better sensed by NCT, and carbon, oxygen, and heavier elements, better sensed by XCT. We have developed a methodology to directly compare structure and hydrogen-loss dynamics measured using neutron imaging with thermogravimetric analysis and differential thermogravimetry and thus can better understand the correlations between hydrogen and carbon release dynamics. While the methodology has been developed for the carbonization of biomass, we expect that it could be applied to in situ dynamic monitoring of other hydrogenous reacting systems with the appropriate spatial and temporal scales.
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- author
- Ossler, Frederik LU ; Finney, Charles E.A. ; Warren, Jeffrey M. ; Bilheux, Jean Christophe ; Zhang, Yuxuan ; Mills, Rebecca A. ; Santodonato, Louis J. and Bilheux, Hassina Z.
- organization
- publishing date
- 2021
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Biomass pyrolysis, Carbonization, Hydrogen loss dynamics, Neutron imaging, Structural dynamics, Thermogravimetry
- in
- Carbon
- volume
- 176
- pages
- 19 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:85101307839
- ISSN
- 0008-6223
- DOI
- 10.1016/j.carbon.2020.11.060
- project
- Hydrogen in biomass pyrolysis and porous carbonaceous matierials: Energy conversion and storage
- language
- English
- LU publication?
- yes
- id
- 56322fbf-7d80-46b4-b713-c86b8bb437e4
- date added to LUP
- 2021-03-08 12:19:28
- date last changed
- 2023-02-02 00:36:08
@article{56322fbf-7d80-46b4-b713-c86b8bb437e4,
abstract = {{<p>We present results from neutron-imaging studies of slow, vacuum pyrolysis of beech, poplar and conifer wood, and pelletized biomass from room temperature up to 1000 °C. A detailed and quantitative method to extract 2D (in situ neutron radiography, NR) and 3D (ex situ neutron computed tomography, NCT) information on structural transformation and elemental hydrogen content has been developed. NCT and X-ray tomography (XCT) experiments on a carbonized beech twig permitted comparison of the spatial distribution of hydrogen, better sensed by NCT, and carbon, oxygen, and heavier elements, better sensed by XCT. We have developed a methodology to directly compare structure and hydrogen-loss dynamics measured using neutron imaging with thermogravimetric analysis and differential thermogravimetry and thus can better understand the correlations between hydrogen and carbon release dynamics. While the methodology has been developed for the carbonization of biomass, we expect that it could be applied to in situ dynamic monitoring of other hydrogenous reacting systems with the appropriate spatial and temporal scales.</p>}},
author = {{Ossler, Frederik and Finney, Charles E.A. and Warren, Jeffrey M. and Bilheux, Jean Christophe and Zhang, Yuxuan and Mills, Rebecca A. and Santodonato, Louis J. and Bilheux, Hassina Z.}},
issn = {{0008-6223}},
keywords = {{Biomass pyrolysis; Carbonization; Hydrogen loss dynamics; Neutron imaging; Structural dynamics; Thermogravimetry}},
language = {{eng}},
pages = {{511--529}},
publisher = {{Elsevier}},
series = {{Carbon}},
title = {{Dynamics of hydrogen loss and structural changes in pyrolyzing biomass utilizing neutron imaging}},
url = {{http://dx.doi.org/10.1016/j.carbon.2020.11.060}},
doi = {{10.1016/j.carbon.2020.11.060}},
volume = {{176}},
year = {{2021}},
}