Chlorine-Free Synthesis of Organic Alkyl Carbonates and Five- and Six-Membered Cyclic Carbonates
(2016) In Advanced Synthesis & Catalysis 358(5). p.834-839- Abstract
This report presents a new, one-pot, facile, selective and green method for methoxycarbonylation of alcohols and synthesis of five- and six-membered cyclic carbonates from corresponding alcohols with dimethyl carbonate (DMC) in the presence of molecular sieves without any additional solvent and catalyst. Syntheses of bifunctional structures comprising a six-membered cyclic carbonate with allyl ether and methacrylate groups, respectively, for different polymerization modes, were also achieved and showed reproducibility on up-scaling the processes.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/5e97e14e-52f6-44aa-8716-330530d74c95
- author
- Pyo, Sang Hyun LU and Hatti-Kaul, Rajni LU
- organization
- publishing date
- 2016-03-03
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- alkyl carbonates, chlorine-free reactions, cyclic carbonates, one-pot carbonylation
- in
- Advanced Synthesis & Catalysis
- volume
- 358
- issue
- 5
- pages
- 6 pages
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- wos:000372132100019
- scopus:84959297459
- ISSN
- 1615-4169
- DOI
- 10.1002/adsc.201500654
- language
- English
- LU publication?
- yes
- id
- 5e97e14e-52f6-44aa-8716-330530d74c95
- date added to LUP
- 2016-06-28 12:49:34
- date last changed
- 2025-01-12 08:05:29
@article{5e97e14e-52f6-44aa-8716-330530d74c95, abstract = {{<p>This report presents a new, one-pot, facile, selective and green method for methoxycarbonylation of alcohols and synthesis of five- and six-membered cyclic carbonates from corresponding alcohols with dimethyl carbonate (DMC) in the presence of molecular sieves without any additional solvent and catalyst. Syntheses of bifunctional structures comprising a six-membered cyclic carbonate with allyl ether and methacrylate groups, respectively, for different polymerization modes, were also achieved and showed reproducibility on up-scaling the processes.</p>}}, author = {{Pyo, Sang Hyun and Hatti-Kaul, Rajni}}, issn = {{1615-4169}}, keywords = {{alkyl carbonates; chlorine-free reactions; cyclic carbonates; one-pot carbonylation}}, language = {{eng}}, month = {{03}}, number = {{5}}, pages = {{834--839}}, publisher = {{John Wiley & Sons Inc.}}, series = {{Advanced Synthesis & Catalysis}}, title = {{Chlorine-Free Synthesis of Organic Alkyl Carbonates and Five- and Six-Membered Cyclic Carbonates}}, url = {{http://dx.doi.org/10.1002/adsc.201500654}}, doi = {{10.1002/adsc.201500654}}, volume = {{358}}, year = {{2016}}, }