Gas Chromatographic Investigation of the Boron Trifluoride Etherate-Induced Formation and Anomerisation of Glucopyranosides
(1998) In Journal of Carbohydrate Chemistry 17(4-5). p.777-784- Abstract
- Boron trifluoride etherate-induced glucosylation of methanol, 1-propanol, 2-propanol, 2-bromoethanol, and 3-bromo-2-(bromomethyl)propan-1-ol, using 1,2,3,4,6-penta-O-acetyl-β-D-glucopyranose as donor, gave the corresponding β-glucopyranosides. The α-glucosides and 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose were formed as byproducts in varying amounts, according to GLC analysis. The propensity of the different glucopyranosides to anomerize was determined in separate experiments.
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https://lup.lub.lu.se/record/650e6b03-3db1-4c0e-9758-ed234be0209c
- author
- Ellervik, Ulf LU ; Jansson, Karl and Magnusson, Göran LU
- organization
- publishing date
- 1998
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Carbohydrate Chemistry
- volume
- 17
- issue
- 4-5
- pages
- 777 - 784
- publisher
- Marcel Dekker
- external identifiers
-
- scopus:0032399596
- ISSN
- 0732-8303
- DOI
- 10.1080/07328309808002351
- language
- English
- LU publication?
- yes
- id
- 650e6b03-3db1-4c0e-9758-ed234be0209c
- date added to LUP
- 2023-08-10 14:59:55
- date last changed
- 2024-02-03 15:53:18
@article{650e6b03-3db1-4c0e-9758-ed234be0209c, abstract = {{Boron trifluoride etherate-induced glucosylation of methanol, 1-propanol, 2-propanol, 2-bromoethanol, and 3-bromo-2-(bromomethyl)propan-1-ol, using 1,2,3,4,6-penta-O-acetyl-β-D-glucopyranose as donor, gave the corresponding β-glucopyranosides. The α-glucosides and 1,2,3,4,6-penta-O-acetyl-α-D-glucopyranose were formed as byproducts in varying amounts, according to GLC analysis. The propensity of the different glucopyranosides to anomerize was determined in separate experiments.}}, author = {{Ellervik, Ulf and Jansson, Karl and Magnusson, Göran}}, issn = {{0732-8303}}, language = {{eng}}, number = {{4-5}}, pages = {{777--784}}, publisher = {{Marcel Dekker}}, series = {{Journal of Carbohydrate Chemistry}}, title = {{Gas Chromatographic Investigation of the Boron Trifluoride Etherate-Induced Formation and Anomerisation of Glucopyranosides}}, url = {{http://dx.doi.org/10.1080/07328309808002351}}, doi = {{10.1080/07328309808002351}}, volume = {{17}}, year = {{1998}}, }