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cis-Bis(dimethyl sulfide)dinitratoplatinum(II) at 295 and 150 K

Hansson, Christian LU and Oskarsson, Åke LU (2007) In Acta Crystallographica. Section C: Crystal Structure Communications 63. p.465-468
Abstract
The title compound, [ Pt( NO3)(2)( C2H6S)(2)], crystallizes in the P2(1)/ n space group ( Z' = 2), with pseudo- square- planar coordination geometry. The complex forms dimers with pseudosymmetry C-i arranged in columns along the b- axis direction, with Pt center dot center dot center dot Pt distances of 6.3056 ( 3) and 4.2382 ( 2) angstrom ( at 150 K). Each column is surrounded by six other columns in a honeycomb rod- like packing. The coordination mode of the nitrate ligands is monodentate, with Pt - O - N angles ranging from similar to 117 to similar to 118 degrees and a tilt between the nitrate ligands and the coordination planes in the range similar to 63 - 70 degrees ( at 150 K). The coordination mode of the nitrate ligands is... (More)
The title compound, [ Pt( NO3)(2)( C2H6S)(2)], crystallizes in the P2(1)/ n space group ( Z' = 2), with pseudo- square- planar coordination geometry. The complex forms dimers with pseudosymmetry C-i arranged in columns along the b- axis direction, with Pt center dot center dot center dot Pt distances of 6.3056 ( 3) and 4.2382 ( 2) angstrom ( at 150 K). Each column is surrounded by six other columns in a honeycomb rod- like packing. The coordination mode of the nitrate ligands is monodentate, with Pt - O - N angles ranging from similar to 117 to similar to 118 degrees and a tilt between the nitrate ligands and the coordination planes in the range similar to 63 - 70 degrees ( at 150 K). The coordination mode of the nitrate ligands is compared with that observed in reported Pt( NO3)(2)L-2 complexes ( where L is a ligand with a donor atom from group 15 or 16), all of which are monodentate, with an average Pt - O - Nangle of 118 ( 2) degrees and a tilt in the range 90 +/- 30 degrees ( with two exceptions, in which the nitrates are approximately in the coordination plane). (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
63
pages
465 - 468
publisher
International Union of Crystallography
external identifiers
  • wos:000249921600017
  • scopus:34948896974
ISSN
0108-2701
DOI
10.1107/S0108270107040504
language
English
LU publication?
yes
id
e98830f4-1137-44d3-9de9-9a67c4e1fae7 (old id 655825)
date added to LUP
2007-12-12 11:22:19
date last changed
2017-01-01 07:12:27
@article{e98830f4-1137-44d3-9de9-9a67c4e1fae7,
  abstract     = {The title compound, [ Pt( NO3)(2)( C2H6S)(2)], crystallizes in the P2(1)/ n space group ( Z' = 2), with pseudo- square- planar coordination geometry. The complex forms dimers with pseudosymmetry C-i arranged in columns along the b- axis direction, with Pt center dot center dot center dot Pt distances of 6.3056 ( 3) and 4.2382 ( 2) angstrom ( at 150 K). Each column is surrounded by six other columns in a honeycomb rod- like packing. The coordination mode of the nitrate ligands is monodentate, with Pt - O - N angles ranging from similar to 117 to similar to 118 degrees and a tilt between the nitrate ligands and the coordination planes in the range similar to 63 - 70 degrees ( at 150 K). The coordination mode of the nitrate ligands is compared with that observed in reported Pt( NO3)(2)L-2 complexes ( where L is a ligand with a donor atom from group 15 or 16), all of which are monodentate, with an average Pt - O - Nangle of 118 ( 2) degrees and a tilt in the range 90 +/- 30 degrees ( with two exceptions, in which the nitrates are approximately in the coordination plane).},
  author       = {Hansson, Christian and Oskarsson, Åke},
  issn         = {0108-2701},
  language     = {eng},
  pages        = {465--468},
  publisher    = {International Union of Crystallography},
  series       = {Acta Crystallographica. Section C: Crystal Structure Communications},
  title        = {cis-Bis(dimethyl sulfide)dinitratoplatinum(II) at 295 and 150 K},
  url          = {http://dx.doi.org/10.1107/S0108270107040504},
  volume       = {63},
  year         = {2007},
}