Probing the valence character of O-1s -> Rydberg excited O-2 by participator Auger decay measurements and partial ion yield spectroscopy following x-ray absorption
(2007) In Journal of Chemical Physics 126(17).- Abstract
- The valence character of O 1s -> Rydberg excited O-2 is investigated by means of participator Auger decay spectroscopy, performed at selected photon energies across the K-shell resonance region, and by means of partial ion yield x-ray absorption spectroscopy. For several of the excitation energies studied, the authors find substantial sigma(*)((4)Sigma(-)(u),(2)Sigma(-)(u)) valence character being mixed with ns sigma and np sigma ((4)Sigma(-)(u),(2)Sigma(-)(u)) Rydberg states. An experimental indication of a coupling between the channels associated with quartet and doublet ion cores is considered and discussed. New spectroscopic constants are derived for the singly ionized X (2)Pi(g) state of O-2 based on the observation of at least 20... (More)
- The valence character of O 1s -> Rydberg excited O-2 is investigated by means of participator Auger decay spectroscopy, performed at selected photon energies across the K-shell resonance region, and by means of partial ion yield x-ray absorption spectroscopy. For several of the excitation energies studied, the authors find substantial sigma(*)((4)Sigma(-)(u),(2)Sigma(-)(u)) valence character being mixed with ns sigma and np sigma ((4)Sigma(-)(u),(2)Sigma(-)(u)) Rydberg states. An experimental indication of a coupling between the channels associated with quartet and doublet ion cores is considered and discussed. New spectroscopic constants are derived for the singly ionized X (2)Pi(g) state of O-2 based on the observation of at least 20 vibrational sublevels. (C) 2007 American Institute of Physics. (Less)
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- author
- organization
- publishing date
- 2007
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 126
- issue
- 17
- article number
- 174304
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000246284800012
- scopus:34248153124
- pmid:17492860
- ISSN
- 0021-9606
- DOI
- 10.1063/1.2723745
- language
- English
- LU publication?
- yes
- id
- b0f1e4c5-5dd0-4668-80f0-f38c9dbe484a (old id 662606)
- date added to LUP
- 2016-04-01 11:45:07
- date last changed
- 2022-01-26 17:40:02
@article{b0f1e4c5-5dd0-4668-80f0-f38c9dbe484a,
abstract = {{The valence character of O 1s -> Rydberg excited O-2 is investigated by means of participator Auger decay spectroscopy, performed at selected photon energies across the K-shell resonance region, and by means of partial ion yield x-ray absorption spectroscopy. For several of the excitation energies studied, the authors find substantial sigma(*)((4)Sigma(-)(u),(2)Sigma(-)(u)) valence character being mixed with ns sigma and np sigma ((4)Sigma(-)(u),(2)Sigma(-)(u)) Rydberg states. An experimental indication of a coupling between the channels associated with quartet and doublet ion cores is considered and discussed. New spectroscopic constants are derived for the singly ionized X (2)Pi(g) state of O-2 based on the observation of at least 20 vibrational sublevels. (C) 2007 American Institute of Physics.}},
author = {{Feifel, R. and Tanaka, T. and Kitajima, M. and Tanaka, H. and De Fanis, A. and Sankari, R. and Karlsson, L. and Ristinmaa Sörensen, Stacey and Piancastelli, M.-N. and Prumper, G. and Hergenhahn, U. and Ueda, K.}},
issn = {{0021-9606}},
language = {{eng}},
number = {{17}},
publisher = {{American Institute of Physics (AIP)}},
series = {{Journal of Chemical Physics}},
title = {{Probing the valence character of O-1s -> Rydberg excited O-2 by participator Auger decay measurements and partial ion yield spectroscopy following x-ray absorption}},
url = {{http://dx.doi.org/10.1063/1.2723745}},
doi = {{10.1063/1.2723745}},
volume = {{126}},
year = {{2007}},
}