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cis-Dichloridobis(diethyl sulfide-kappa S) platinum(II) at 295 and 150 K

Hansson, Christian LU (2007) In Acta Crystallographica. Section C: Crystal Structure Communications 63. p.361-363
Abstract
The title compound, cis-[ PtCl2( C4H10S) (2)], crystallizes in the space group P21/ n with pseudo- square- planar coordination geometry. The orientation of the ethyl groups on the S atoms is staggered with respect to the coordination plane, giving the complex approximate C(2)v symmetry. The complex does not form dimeric packing units with short Pt center dot center dot center dot S intradimeric distances as seen in some related complexes, but instead displays C - H center dot center dot center dot Cl interactions in three dimensions. These C - H center dot center dot center dot Cl - Pt contacts are compared with those of related compounds reported in the Cambridge Structural Database, which show a frequency maximum in the range 120 - 170... (More)
The title compound, cis-[ PtCl2( C4H10S) (2)], crystallizes in the space group P21/ n with pseudo- square- planar coordination geometry. The orientation of the ethyl groups on the S atoms is staggered with respect to the coordination plane, giving the complex approximate C(2)v symmetry. The complex does not form dimeric packing units with short Pt center dot center dot center dot S intradimeric distances as seen in some related complexes, but instead displays C - H center dot center dot center dot Cl interactions in three dimensions. These C - H center dot center dot center dot Cl - Pt contacts are compared with those of related compounds reported in the Cambridge Structural Database, which show a frequency maximum in the range 120 - 170 degrees for the C - H center dot center dot Cl angle. (Less)
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
63
pages
361 - 363
publisher
International Union of Crystallography
external identifiers
  • wos:000248488100013
  • scopus:34547812661
ISSN
0108-2701
DOI
10.1107/S0108270107030417
language
English
LU publication?
yes
id
515f2ad8-6d00-480f-9e45-f85853fd75a8 (old id 686946)
date added to LUP
2007-12-12 11:24:22
date last changed
2017-01-01 07:10:49
@article{515f2ad8-6d00-480f-9e45-f85853fd75a8,
  abstract     = {The title compound, cis-[ PtCl2( C4H10S) (2)], crystallizes in the space group P21/ n with pseudo- square- planar coordination geometry. The orientation of the ethyl groups on the S atoms is staggered with respect to the coordination plane, giving the complex approximate C(2)v symmetry. The complex does not form dimeric packing units with short Pt center dot center dot center dot S intradimeric distances as seen in some related complexes, but instead displays C - H center dot center dot center dot Cl interactions in three dimensions. These C - H center dot center dot center dot Cl - Pt contacts are compared with those of related compounds reported in the Cambridge Structural Database, which show a frequency maximum in the range 120 - 170 degrees for the C - H center dot center dot Cl angle.},
  author       = {Hansson, Christian},
  issn         = {0108-2701},
  language     = {eng},
  pages        = {361--363},
  publisher    = {International Union of Crystallography},
  series       = {Acta Crystallographica. Section C: Crystal Structure Communications},
  title        = {cis-Dichloridobis(diethyl sulfide-kappa S) platinum(II) at 295 and 150 K},
  url          = {http://dx.doi.org/10.1107/S0108270107030417},
  volume       = {63},
  year         = {2007},
}