cis-Dichloridobis(diethyl sulfide-kappa S) platinum(II) at 295 and 150 K
(2007) In Acta Crystallographica. Section C: Crystal Structure Communications 63. p.361-363- Abstract
- The title compound, cis-[ PtCl2( C4H10S) (2)], crystallizes in the space group P21/ n with pseudo- square- planar coordination geometry. The orientation of the ethyl groups on the S atoms is staggered with respect to the coordination plane, giving the complex approximate C(2)v symmetry. The complex does not form dimeric packing units with short Pt center dot center dot center dot S intradimeric distances as seen in some related complexes, but instead displays C - H center dot center dot center dot Cl interactions in three dimensions. These C - H center dot center dot center dot Cl - Pt contacts are compared with those of related compounds reported in the Cambridge Structural Database, which show a frequency maximum in the range 120 - 170... (More)
- The title compound, cis-[ PtCl2( C4H10S) (2)], crystallizes in the space group P21/ n with pseudo- square- planar coordination geometry. The orientation of the ethyl groups on the S atoms is staggered with respect to the coordination plane, giving the complex approximate C(2)v symmetry. The complex does not form dimeric packing units with short Pt center dot center dot center dot S intradimeric distances as seen in some related complexes, but instead displays C - H center dot center dot center dot Cl interactions in three dimensions. These C - H center dot center dot center dot Cl - Pt contacts are compared with those of related compounds reported in the Cambridge Structural Database, which show a frequency maximum in the range 120 - 170 degrees for the C - H center dot center dot Cl angle. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/686946
- author
- Hansson, Christian LU
- organization
- publishing date
- 2007
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Acta Crystallographica. Section C: Crystal Structure Communications
- volume
- 63
- pages
- 361 - 363
- publisher
- International Union of Crystallography
- external identifiers
-
- wos:000248488100013
- scopus:34547812661
- pmid:17675684
- ISSN
- 0108-2701
- DOI
- 10.1107/S0108270107030417
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
- id
- 515f2ad8-6d00-480f-9e45-f85853fd75a8 (old id 686946)
- date added to LUP
- 2016-04-01 16:38:32
- date last changed
- 2022-01-28 21:06:46
@article{515f2ad8-6d00-480f-9e45-f85853fd75a8,
abstract = {{The title compound, cis-[ PtCl2( C4H10S) (2)], crystallizes in the space group P21/ n with pseudo- square- planar coordination geometry. The orientation of the ethyl groups on the S atoms is staggered with respect to the coordination plane, giving the complex approximate C(2)v symmetry. The complex does not form dimeric packing units with short Pt center dot center dot center dot S intradimeric distances as seen in some related complexes, but instead displays C - H center dot center dot center dot Cl interactions in three dimensions. These C - H center dot center dot center dot Cl - Pt contacts are compared with those of related compounds reported in the Cambridge Structural Database, which show a frequency maximum in the range 120 - 170 degrees for the C - H center dot center dot Cl angle.}},
author = {{Hansson, Christian}},
issn = {{0108-2701}},
language = {{eng}},
pages = {{361--363}},
publisher = {{International Union of Crystallography}},
series = {{Acta Crystallographica. Section C: Crystal Structure Communications}},
title = {{cis-Dichloridobis(diethyl sulfide-kappa S) platinum(II) at 295 and 150 K}},
url = {{http://dx.doi.org/10.1107/S0108270107030417}},
doi = {{10.1107/S0108270107030417}},
volume = {{63}},
year = {{2007}},
}