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Unprecedented enantioselectivity in a cluster-based catalytic system

Moberg, Viktor LU ; Haukka, Matti; Koshevoy, Igor LU ; Ortiz, Roberto LU and Nordlander, Ebbe LU (2007) In Organometallics 26(17). p.4090-4093
Abstract
Catalytic systems based on the clusters [H4RU4(CO)(10)-{mu-1,2-(P-P)}] and [H4RU4(CO)(10){1,1-(P-P)}] (P-P = (R)-(R)-Ph(2)PPhFcCHCH(3)PR(2); Fc = ferrocenyl; R = 3,5-CF3Ph (W001), Ph (W002)) have been used successfully in asymmetric hydrogenation of prochiral alpha-unsaturated carboxylic acids under mild conditions. Enantiomeric excesses of 42-92% and conversion rates in excess of 99% were observed.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organometallics
volume
26
issue
17
pages
4090 - 4093
publisher
The American Chemical Society
external identifiers
  • wos:000248729400002
  • scopus:34548178516
ISSN
1520-6041
DOI
10.1021/om070211d
language
English
LU publication?
yes
id
aab2b363-2b63-4618-bc15-556e590cd528 (old id 693132)
date added to LUP
2007-12-18 11:18:20
date last changed
2017-10-22 03:56:15
@article{aab2b363-2b63-4618-bc15-556e590cd528,
  abstract     = {Catalytic systems based on the clusters [H4RU4(CO)(10)-{mu-1,2-(P-P)}] and [H4RU4(CO)(10){1,1-(P-P)}] (P-P = (R)-(R)-Ph(2)PPhFcCHCH(3)PR(2); Fc = ferrocenyl; R = 3,5-CF3Ph (W001), Ph (W002)) have been used successfully in asymmetric hydrogenation of prochiral alpha-unsaturated carboxylic acids under mild conditions. Enantiomeric excesses of 42-92% and conversion rates in excess of 99% were observed.},
  author       = {Moberg, Viktor and Haukka, Matti and Koshevoy, Igor and Ortiz, Roberto and Nordlander, Ebbe},
  issn         = {1520-6041},
  language     = {eng},
  number       = {17},
  pages        = {4090--4093},
  publisher    = {The American Chemical Society},
  series       = {Organometallics},
  title        = {Unprecedented enantioselectivity in a cluster-based catalytic system},
  url          = {http://dx.doi.org/10.1021/om070211d},
  volume       = {26},
  year         = {2007},
}