Adipic and Malonic Acid Aqueous Solutions: Surface Tensions and Saturation Vapor Pressures
(2007) In The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory 111(50). p.12995-13002- Abstract
- The surface tension of adipic aqueous solution has been measured as a function of temperature (T = 278-313 K) and adipic acid mole fraction (X = 0.000-0.003) using the Wilhelmy plate method. A parameterization fitted to these data is presented. The evaporation rates of binary water-malonic and water-adipic acid droplets have been measured with a TDMA-technique at different temperatures (T = 293-300 K) and relative humidities (58-80 %), and the saturation vapor pressures of subcooled liquid malonic and adipic acids have been derived from the data using a binary evaporation model.
The temperature dependence of the vapor pressures was obtained as least squares fits to the derived vapor pressures: ln (psat,l) [Pa] = 220.2389... (More) - The surface tension of adipic aqueous solution has been measured as a function of temperature (T = 278-313 K) and adipic acid mole fraction (X = 0.000-0.003) using the Wilhelmy plate method. A parameterization fitted to these data is presented. The evaporation rates of binary water-malonic and water-adipic acid droplets have been measured with a TDMA-technique at different temperatures (T = 293-300 K) and relative humidities (58-80 %), and the saturation vapor pressures of subcooled liquid malonic and adipic acids have been derived from the data using a binary evaporation model.
The temperature dependence of the vapor pressures was obtained as least squares fits to the derived vapor pressures: ln (psat,l) [Pa] = 220.2389 – 22634.96/T [K] – 26.66767lnT [K] for malonic acid, and ln (psat,l) [Pa] = 140.6704 – 18230.97/T [K] – 15.48011lnT [K] for adipic acid. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/773784
- author
- Riipinen, Ilona ; Koponen, Ismo K. ; Frank, Göran LU ; Hyvärinen, Antti-Pekka ; Vanhanen, Joonas ; Lihavainen, Heikki ; Lehtinen, Kari E. J. ; Bilde, Merete and Kulmala, Markku
- organization
- publishing date
- 2007
- type
- Contribution to journal
- publication status
- published
- subject
- in
- The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
- volume
- 111
- issue
- 50
- pages
- 12995 - 13002
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:38149120327
- ISSN
- 1520-5215
- DOI
- 10.1021/jp073731v
- language
- English
- LU publication?
- no
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Nuclear Physics (Faculty of Technology) (011013007)
- id
- 6bf39e66-d4ea-4d81-9a56-801a974b7440 (old id 773784)
- date added to LUP
- 2016-04-01 17:04:01
- date last changed
- 2022-01-29 00:06:34
@article{6bf39e66-d4ea-4d81-9a56-801a974b7440, abstract = {{The surface tension of adipic aqueous solution has been measured as a function of temperature (T = 278-313 K) and adipic acid mole fraction (X = 0.000-0.003) using the Wilhelmy plate method. A parameterization fitted to these data is presented. The evaporation rates of binary water-malonic and water-adipic acid droplets have been measured with a TDMA-technique at different temperatures (T = 293-300 K) and relative humidities (58-80 %), and the saturation vapor pressures of subcooled liquid malonic and adipic acids have been derived from the data using a binary evaporation model.<br/><br> <br/><br> The temperature dependence of the vapor pressures was obtained as least squares fits to the derived vapor pressures: ln (psat,l) [Pa] = 220.2389 – 22634.96/T [K] – 26.66767lnT [K] for malonic acid, and ln (psat,l) [Pa] = 140.6704 – 18230.97/T [K] – 15.48011lnT [K] for adipic acid.}}, author = {{Riipinen, Ilona and Koponen, Ismo K. and Frank, Göran and Hyvärinen, Antti-Pekka and Vanhanen, Joonas and Lihavainen, Heikki and Lehtinen, Kari E. J. and Bilde, Merete and Kulmala, Markku}}, issn = {{1520-5215}}, language = {{eng}}, number = {{50}}, pages = {{12995--13002}}, publisher = {{The American Chemical Society (ACS)}}, series = {{The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory}}, title = {{Adipic and Malonic Acid Aqueous Solutions: Surface Tensions and Saturation Vapor Pressures}}, url = {{http://dx.doi.org/10.1021/jp073731v}}, doi = {{10.1021/jp073731v}}, volume = {{111}}, year = {{2007}}, }