Advanced

A Diels-Alder Approach to a Communesin Model: A/B-Cyclization Route

Sanzone, Angelo LU and Somfai, Peter LU (2015) In European Journal of Organic Chemistry p.3441-3449
Abstract
Compound 3, a model system for communesin F, was approached by using a Diels-Alder reaction for the introduction of the vicinal quaternary stereocentres. Subsequent introduction of A/B-ring system followed by D/E-ring closure gave hexacyclic system 22. All attempts to reduce this material to give compound 3 were, however, unproductive.
Please use this url to cite or link to this publication:
author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Polycycles, Alkaloids, Natural products, Cyclization, Synthesis design
in
European Journal of Organic Chemistry
issue
16
pages
3441 - 3449
publisher
John Wiley & Sons
external identifiers
  • wos:000355265000006
  • scopus:84934873244
ISSN
1434-193X
DOI
10.1002/ejoc.201500177
language
English
LU publication?
yes
id
2e589828-4e53-4a8d-bd37-c7fb3501e853 (old id 7410597)
date added to LUP
2015-06-29 12:28:00
date last changed
2017-08-06 03:16:35
@article{2e589828-4e53-4a8d-bd37-c7fb3501e853,
  abstract     = {Compound 3, a model system for communesin F, was approached by using a Diels-Alder reaction for the introduction of the vicinal quaternary stereocentres. Subsequent introduction of A/B-ring system followed by D/E-ring closure gave hexacyclic system 22. All attempts to reduce this material to give compound 3 were, however, unproductive.},
  author       = {Sanzone, Angelo and Somfai, Peter},
  issn         = {1434-193X},
  keyword      = {Polycycles,Alkaloids,Natural products,Cyclization,Synthesis design},
  language     = {eng},
  number       = {16},
  pages        = {3441--3449},
  publisher    = {John Wiley & Sons},
  series       = {European Journal of Organic Chemistry},
  title        = {A Diels-Alder Approach to a Communesin Model: A/B-Cyclization Route},
  url          = {http://dx.doi.org/10.1002/ejoc.201500177},
  year         = {2015},
}