"Hidden"" vibrations in CO: reinvestigation of resonant Auger decay for the C 1s to pi /sup */ excitation
Feifel, Raimund ; karlsson, Leif and Ristinmaa Sörensen, Stacey LU
(2002)
In Physical Review A
65(5).
p.52701-52701
- Abstract
- We report an experimental investigation of higher vibrational levels (ν′>2) of the C 1s→π* excitation in CO utilizing resonant Auger electron spectroscopy. These vibrational states are not readily seen in a total yield absorption spectrum, whereas they are shown to be discernable in a partial electron yield spectrum. Furthermore, the nature of the spectator part between EBin=26.5 and 30 eV, being subject of an ongoing debate, is discussed on the grounds of the presented experimental data. The experiments indicate that the formally used adiabatic framework for the multitude of close lying 2Π potential curves is inappropriate, but that a diabatic treatment can be used for the interpretation of the spectra.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/762302
- author
- Feifel, Raimund
; karlsson, Leif
and Ristinmaa Sörensen, Stacey
LU
- organization
- publishing date
- 2002
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review A
- volume
- 65
- issue
- 5
- pages
- 52701 - 52701
- publisher
- American Physical Society
- external identifiers
-
- wos:000175743800082
- scopus:85037223327
- DOI
- 10.1103/PhysRevA.65.052701
- language
- English
- LU publication?
- yes
- id
- 0e8d7103-88b3-4251-9630-331d6f837e07 (old id 762302)
- date added to LUP
- 2016-04-04 10:06:58
- date last changed
- 2024-01-12 18:54:28
@article{0e8d7103-88b3-4251-9630-331d6f837e07,
abstract = {{We report an experimental investigation of higher vibrational levels (ν′>2) of the C 1s→π* excitation in CO utilizing resonant Auger electron spectroscopy. These vibrational states are not readily seen in a total yield absorption spectrum, whereas they are shown to be discernable in a partial electron yield spectrum. Furthermore, the nature of the spectator part between EBin=26.5 and 30 eV, being subject of an ongoing debate, is discussed on the grounds of the presented experimental data. The experiments indicate that the formally used adiabatic framework for the multitude of close lying 2Π potential curves is inappropriate, but that a diabatic treatment can be used for the interpretation of the spectra.}},
author = {{Feifel, Raimund and karlsson, Leif and Ristinmaa Sörensen, Stacey}},
language = {{eng}},
number = {{5}},
pages = {{52701--52701}},
publisher = {{American Physical Society}},
series = {{Physical Review A}},
title = {{"Hidden"" vibrations in CO: reinvestigation of resonant Auger decay for the C 1s to pi /sup */ excitation}},
url = {{http://dx.doi.org/10.1103/PhysRevA.65.052701}},
doi = {{10.1103/PhysRevA.65.052701}},
volume = {{65}},
year = {{2002}},
}