Variation in crystalline architectures through supramolecular interactions in copper(II) complexes with tridentate N2O donor Schiff bases
(2015) In Journal of Coordination Chemistry 68(14). p.2520-2538- Abstract
- Three copper(II) complexes, [Cu(L-1)(H2O)(ClO4)]0.5H(2)O (1), [Cu(L-2)(H2O)(ClO4)]0.5H(2)O (2), and [Cu(L-2)(NCNC(OCH3)NH2)]ClO4 (3), where HL1=4-bromo-2-(-(quinolin-8-ylimino)methyl)phenol and HL2=1-(-(quinolin-8-ylimino)methyl)naphthalen-2-ol, have been prepared and characterized by elemental analysis, IR, UV-vis and fluorescence spectroscopy and single-crystal X-ray diffraction studies. The copper(II) centers assume five-coordinate square-pyramidal geometries in 1 and 2, whereas square planar copper(II) is present in 3. A methanol molecule has been inserted in the pendant end of the ligated dicyanamide in 3. Various supramolecular architectures are formed by hydrogen bonding, , C-H, and lp interactions.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/7790596
- author
- Jana, Subrata ; Jana, Partha LU and Chattopadhyay, Shouvik
- organization
- publishing date
- 2015
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Copper(II), Schiff base, Crystal structure, Supramolecular interactions, Methanol insertion
- in
- Journal of Coordination Chemistry
- volume
- 68
- issue
- 14
- pages
- 2520 - 2538
- publisher
- Taylor & Francis
- external identifiers
-
- wos:000357867600011
- scopus:84954025855
- ISSN
- 1026-7441
- DOI
- 10.1080/00958972.2015.1043907
- language
- English
- LU publication?
- yes
- id
- 253789a5-0c8e-411c-b4dc-3a5d5fcba0e6 (old id 7790596)
- date added to LUP
- 2016-04-01 10:28:21
- date last changed
- 2022-03-12 06:13:35
@article{253789a5-0c8e-411c-b4dc-3a5d5fcba0e6, abstract = {{Three copper(II) complexes, [Cu(L-1)(H2O)(ClO4)]0.5H(2)O (1), [Cu(L-2)(H2O)(ClO4)]0.5H(2)O (2), and [Cu(L-2)(NCNC(OCH3)NH2)]ClO4 (3), where HL1=4-bromo-2-(-(quinolin-8-ylimino)methyl)phenol and HL2=1-(-(quinolin-8-ylimino)methyl)naphthalen-2-ol, have been prepared and characterized by elemental analysis, IR, UV-vis and fluorescence spectroscopy and single-crystal X-ray diffraction studies. The copper(II) centers assume five-coordinate square-pyramidal geometries in 1 and 2, whereas square planar copper(II) is present in 3. A methanol molecule has been inserted in the pendant end of the ligated dicyanamide in 3. Various supramolecular architectures are formed by hydrogen bonding, , C-H, and lp interactions.}}, author = {{Jana, Subrata and Jana, Partha and Chattopadhyay, Shouvik}}, issn = {{1026-7441}}, keywords = {{Copper(II); Schiff base; Crystal structure; Supramolecular interactions; Methanol insertion}}, language = {{eng}}, number = {{14}}, pages = {{2520--2538}}, publisher = {{Taylor & Francis}}, series = {{Journal of Coordination Chemistry}}, title = {{Variation in crystalline architectures through supramolecular interactions in copper(II) complexes with tridentate N2O donor Schiff bases}}, url = {{http://dx.doi.org/10.1080/00958972.2015.1043907}}, doi = {{10.1080/00958972.2015.1043907}}, volume = {{68}}, year = {{2015}}, }