Synthesis, Characterization and Catalytic Activity Studies of Rhenium Carbonyl Complexes Containing Chiral Diphosphines of the Josiphos and Walphos Families
(2015) In Journal of Cluster Science 26(4). p.1231-1252- Abstract
- Ten rhenium carbonyl complexes-[Re(H)(CO)(3)(1a)], [Re-3(mu-H)(3)(CO)(10) (1a)], [Re-2(CO)(9)(2a)], [Re-2(CO)(8)(2a)], [Re-2(CO)(9)(2b)], [{Re-2(CO)(9)}(2)(2b)], [Re-2 (CO)(8)(2b)], [Re-2(CO)(8)(1b)], [Re-2(mu-H)(2)(CO)(6)(2b)] and [Re-3(mu-H)(3)(CO)(11)(2b)]-containing different bidentate chiral phosphine ligands of the Josiphos (1a, 1b) and Walphos (2a, 2b) families have been synthesized and fully characterized (1a: (R)-1-{(S-P)-2-[Bis[3,5-bis(trifluoromethyl) phenyl] phosphino] ferrocenyl} ethyldi(3,5-xylyl) phosphine, 1b: (R)-1-{(S-P)-2-[Di(2-furyl) phosphino] ferrocenyl} ethyldi-tert-butylphosphine, 2a: (R)-1-{(R-P)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl) phosphino] phenyl] ferrocenyl} ethylbis[3,5-bis(trifluoromethyl) phenyl]... (More)
- Ten rhenium carbonyl complexes-[Re(H)(CO)(3)(1a)], [Re-3(mu-H)(3)(CO)(10) (1a)], [Re-2(CO)(9)(2a)], [Re-2(CO)(8)(2a)], [Re-2(CO)(9)(2b)], [{Re-2(CO)(9)}(2)(2b)], [Re-2 (CO)(8)(2b)], [Re-2(CO)(8)(1b)], [Re-2(mu-H)(2)(CO)(6)(2b)] and [Re-3(mu-H)(3)(CO)(11)(2b)]-containing different bidentate chiral phosphine ligands of the Josiphos (1a, 1b) and Walphos (2a, 2b) families have been synthesized and fully characterized (1a: (R)-1-{(S-P)-2-[Bis[3,5-bis(trifluoromethyl) phenyl] phosphino] ferrocenyl} ethyldi(3,5-xylyl) phosphine, 1b: (R)-1-{(S-P)-2-[Di(2-furyl) phosphino] ferrocenyl} ethyldi-tert-butylphosphine, 2a: (R)-1-{(R-P)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl) phosphino] phenyl] ferrocenyl} ethylbis[3,5-bis(trifluoromethyl) phenyl] phosphine and 2b: (R)-1-{(R-P)-2-[2( Diphenylphosphino) phenyl] ferrocenyl} ethyldicyclohexylphosphine). The phosphine-substituted clusters were tested for hydrogenation of tiglic acid [trans-2-methyl-2-butenoic acid]. The catalytic reactions gave reasonable conversion rates (15-88 %) under relatively mild conditions but relatively moderate enantiomeric excesses (8-57 %) were observed. The crystal structures of [ReH(CO)(3)(1a)], [Re-2 (CO)(9)(2a)], [{Re-2(CO)(9)}(2)(2b)] and [Re-2(mu-H)(2)(CO)(6)(2b)] are presented. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/7791073
- author
- Abdel-Magied, Ahmed F. ; Patil, Manjula LU ; Singh, Amrendra LU ; Haukka, Matti ; Monari, Magda and Nordlander, Ebbe LU
- organization
- publishing date
- 2015
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Cluster, Rhenium, Asymmetric hydrogenation, Homogeneous catalysis
- in
- Journal of Cluster Science
- volume
- 26
- issue
- 4
- pages
- 1231 - 1252
- publisher
- Springer
- external identifiers
-
- wos:000357120700016
- scopus:84934444420
- ISSN
- 1040-7278
- DOI
- 10.1007/s10876-014-0809-y
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
- id
- d7ecd962-6186-4958-80ce-f35aa8345154 (old id 7791073)
- date added to LUP
- 2016-04-01 12:51:37
- date last changed
- 2022-01-27 08:01:31
@article{d7ecd962-6186-4958-80ce-f35aa8345154,
abstract = {{Ten rhenium carbonyl complexes-[Re(H)(CO)(3)(1a)], [Re-3(mu-H)(3)(CO)(10) (1a)], [Re-2(CO)(9)(2a)], [Re-2(CO)(8)(2a)], [Re-2(CO)(9)(2b)], [{Re-2(CO)(9)}(2)(2b)], [Re-2 (CO)(8)(2b)], [Re-2(CO)(8)(1b)], [Re-2(mu-H)(2)(CO)(6)(2b)] and [Re-3(mu-H)(3)(CO)(11)(2b)]-containing different bidentate chiral phosphine ligands of the Josiphos (1a, 1b) and Walphos (2a, 2b) families have been synthesized and fully characterized (1a: (R)-1-{(S-P)-2-[Bis[3,5-bis(trifluoromethyl) phenyl] phosphino] ferrocenyl} ethyldi(3,5-xylyl) phosphine, 1b: (R)-1-{(S-P)-2-[Di(2-furyl) phosphino] ferrocenyl} ethyldi-tert-butylphosphine, 2a: (R)-1-{(R-P)-2-[2-[Bis(4-methoxy-3,5-dimethylphenyl) phosphino] phenyl] ferrocenyl} ethylbis[3,5-bis(trifluoromethyl) phenyl] phosphine and 2b: (R)-1-{(R-P)-2-[2( Diphenylphosphino) phenyl] ferrocenyl} ethyldicyclohexylphosphine). The phosphine-substituted clusters were tested for hydrogenation of tiglic acid [trans-2-methyl-2-butenoic acid]. The catalytic reactions gave reasonable conversion rates (15-88 %) under relatively mild conditions but relatively moderate enantiomeric excesses (8-57 %) were observed. The crystal structures of [ReH(CO)(3)(1a)], [Re-2 (CO)(9)(2a)], [{Re-2(CO)(9)}(2)(2b)] and [Re-2(mu-H)(2)(CO)(6)(2b)] are presented.}},
author = {{Abdel-Magied, Ahmed F. and Patil, Manjula and Singh, Amrendra and Haukka, Matti and Monari, Magda and Nordlander, Ebbe}},
issn = {{1040-7278}},
keywords = {{Cluster; Rhenium; Asymmetric hydrogenation; Homogeneous catalysis}},
language = {{eng}},
number = {{4}},
pages = {{1231--1252}},
publisher = {{Springer}},
series = {{Journal of Cluster Science}},
title = {{Synthesis, Characterization and Catalytic Activity Studies of Rhenium Carbonyl Complexes Containing Chiral Diphosphines of the Josiphos and Walphos Families}},
url = {{http://dx.doi.org/10.1007/s10876-014-0809-y}},
doi = {{10.1007/s10876-014-0809-y}},
volume = {{26}},
year = {{2015}},
}