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The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]

Kostakis, George ; Xydias, Pantelis ; Nordlander, Ebbe LU and Plakatouras, John C. (2012) In Inorganica Chimica Acta 383. p.327-331
Abstract
The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.
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keywords
Copper, 3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2, [1-(4-((1H-benzo[d][1, 3]triazole], Complex, X-ray
in
Inorganica Chimica Acta
volume
383
pages
327 - 331
publisher
Elsevier
external identifiers
  • wos:000300623600049
  • scopus:84857234259
ISSN
0020-1693
DOI
10.1016/j.ica.2011.10.063
language
English
LU publication?
yes
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The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
779fb62d-3dfe-49e3-a481-c40eaf953821 (old id 2390712)
date added to LUP
2016-04-01 14:38:26
date last changed
2022-01-28 01:46:57
@article{779fb62d-3dfe-49e3-a481-c40eaf953821,
  abstract     = {{The reaction of the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole] (L) with CuCl2 in acetonitrile yields a dinuclear copper(II) complex [Cu2Cl4L2]center dot 2CH(3)CN (1.2CH3CN), which has been characterized by elemental analysis, powder and single crystal X-ray diffraction, thermal gravimetric analysis as well as IR, UV-Vis and EPR spectroscopy The crystal structure reveals that the metal coordination geometry is best described as square planar. (C) 2011 Elsevier B. V. All rights reserved.}},
  author       = {{Kostakis, George and Xydias, Pantelis and Nordlander, Ebbe and Plakatouras, John C.}},
  issn         = {{0020-1693}},
  keywords     = {{Copper; 3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1; 2; [1-(4-((1H-benzo[d][1; 3]triazole]; Complex; X-ray}},
  language     = {{eng}},
  pages        = {{327--331}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{The first structural determination of a copper (II) complex containing the ligand [1-(4-((1H-benzo[d][1,2,3]triazol-2(3H)-yl)methyl)benzyl)-1H-benzo[d][1, 2,3]triazole]}},
  url          = {{http://dx.doi.org/10.1016/j.ica.2011.10.063}},
  doi          = {{10.1016/j.ica.2011.10.063}},
  volume       = {{383}},
  year         = {{2012}},
}