Copper(I) Catalyzed Decarboxylative Synthesis of Diareno[ a, e]cyclooctatetraenes
(2022) In Journal of Organic Chemistry 87(11). p.7501-7508- Abstract
Diareno[a,e]cyclooctatetraenes find widespread applications as building blocks, ligands, and responsive cores in topologically switchable materials. However, current synthetic methods to these structures suffer from low yields or operational disadvantages. Here, we describe a practical three-step approach to diareno[a,e]cyclooctatetraenes using an efficient copper(I) catalyzed double decarboxylation as the key step. The sequence relies on cheap and abundant reagents, is readily performed on scale, and is amenable also to unsymmetrical derivatives that expand the utility of this intriguing class of structures.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/783fe776-ef25-41b1-bb0e-2a1adf9983e5
- author
- Tasić, Magdalena LU ; Ruiz-Soriano, Albert and Strand, Daniel LU
- organization
- publishing date
- 2022-06-03
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Organic Chemistry
- volume
- 87
- issue
- 11
- pages
- 7501 - 7508
- publisher
- The American Chemical Society (ACS)
- external identifiers
-
- scopus:85131415217
- pmid:35587005
- ISSN
- 0022-3263
- DOI
- 10.1021/acs.joc.2c00286
- language
- English
- LU publication?
- yes
- id
- 783fe776-ef25-41b1-bb0e-2a1adf9983e5
- date added to LUP
- 2022-08-18 14:33:17
- date last changed
- 2024-06-26 06:38:22
@article{783fe776-ef25-41b1-bb0e-2a1adf9983e5, abstract = {{<p>Diareno[a,e]cyclooctatetraenes find widespread applications as building blocks, ligands, and responsive cores in topologically switchable materials. However, current synthetic methods to these structures suffer from low yields or operational disadvantages. Here, we describe a practical three-step approach to diareno[a,e]cyclooctatetraenes using an efficient copper(I) catalyzed double decarboxylation as the key step. The sequence relies on cheap and abundant reagents, is readily performed on scale, and is amenable also to unsymmetrical derivatives that expand the utility of this intriguing class of structures.</p>}}, author = {{Tasić, Magdalena and Ruiz-Soriano, Albert and Strand, Daniel}}, issn = {{0022-3263}}, language = {{eng}}, month = {{06}}, number = {{11}}, pages = {{7501--7508}}, publisher = {{The American Chemical Society (ACS)}}, series = {{Journal of Organic Chemistry}}, title = {{Copper(I) Catalyzed Decarboxylative Synthesis of Diareno[ a, e]cyclooctatetraenes}}, url = {{http://dx.doi.org/10.1021/acs.joc.2c00286}}, doi = {{10.1021/acs.joc.2c00286}}, volume = {{87}}, year = {{2022}}, }