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Chiral platinum(II) complexes. Crystal and molecular structures of cis-[PtPhCl((R,R)-CHIRAPHOS)] and cis-[PtCl2((R,R)-CHIRAPHOS)]

Johansson, Maria H. LU ; Malmström, Torsten LU and Wendt, Ola F. LU (2001) In Inorganica Chimica Acta 316(1-2). p.149-152
Abstract

The reaction between trans-PtPhCl(SMe2)2 and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P21 with a = 12.875(3), b = 18.012(4), c = 13.864(3) Å, β = 109.71(3)° and Z = 4. In CDCl3 1 reacts with Ph2P(C6H4)CH2N(Me)(COEt) to give cis[PtCl2((R,R)-CHIRAPHOS)] (2), the crystals of which are monoclinic, space group P21 with a = 7.8052(16), b = 17.679(4), c = 9.843(2) Å, β = 100.67(3)° and Z = 2.

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; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Chiral phosphine complexes, Crystal structures, Platinum complexes
in
Inorganica Chimica Acta
volume
316
issue
1-2
pages
4 pages
publisher
Elsevier
external identifiers
  • scopus:0035821324
ISSN
0020-1693
DOI
10.1016/S0020-1693(01)00396-6
language
English
LU publication?
yes
id
78d4525c-edc3-4233-8f3c-ac4fae8728ab
date added to LUP
2019-05-03 15:11:47
date last changed
2020-01-13 01:42:57
@article{78d4525c-edc3-4233-8f3c-ac4fae8728ab,
  abstract     = {<p>The reaction between trans-PtPhCl(SMe<sub>2</sub>)<sub>2</sub> and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P2<sub>1</sub> with a = 12.875(3), b = 18.012(4), c = 13.864(3) Å, β = 109.71(3)° and Z = 4. In CDCl<sub>3</sub> 1 reacts with Ph<sub>2</sub>P(C<sub>6</sub>H<sub>4</sub>)CH<sub>2</sub>N(Me)(COEt) to give cis[PtCl<sub>2</sub>((R,R)-CHIRAPHOS)] (2), the crystals of which are monoclinic, space group P2<sub>1</sub> with a = 7.8052(16), b = 17.679(4), c = 9.843(2) Å, β = 100.67(3)° and Z = 2.</p>},
  author       = {Johansson, Maria H. and Malmström, Torsten and Wendt, Ola F.},
  issn         = {0020-1693},
  language     = {eng},
  month        = {05},
  number       = {1-2},
  pages        = {149--152},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {Chiral platinum(II) complexes. Crystal and molecular structures of cis-[PtPhCl((R,R)-CHIRAPHOS)] and cis-[PtCl<sub>2</sub>((R,R)-CHIRAPHOS)]},
  url          = {http://dx.doi.org/10.1016/S0020-1693(01)00396-6},
  doi          = {10.1016/S0020-1693(01)00396-6},
  volume       = {316},
  year         = {2001},
}