Chiral platinum(II) complexes. Crystal and molecular structures of cis-[PtPhCl((R,R)-CHIRAPHOS)] and cis-[PtCl2((R,R)-CHIRAPHOS)]
(2001) In Inorganica Chimica Acta 316(1-2). p.149-152- Abstract
The reaction between trans-PtPhCl(SMe2)2 and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P21 with a = 12.875(3), b = 18.012(4), c = 13.864(3) Å, β = 109.71(3)° and Z = 4. In CDCl3 1 reacts with Ph2P(C6H4)CH2N(Me)(COEt) to give cis[PtCl2((R,R)-CHIRAPHOS)] (2), the crystals of which are monoclinic, space group P21 with a = 7.8052(16), b = 17.679(4), c = 9.843(2) Å, β = 100.67(3)° and Z = 2.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/78d4525c-edc3-4233-8f3c-ac4fae8728ab
- author
- Johansson, Maria H. LU ; Malmström, Torsten LU and Wendt, Ola F. LU
- organization
- publishing date
- 2001-05-07
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Chiral phosphine complexes, Crystal structures, Platinum complexes
- in
- Inorganica Chimica Acta
- volume
- 316
- issue
- 1-2
- pages
- 4 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:0035821324
- ISSN
- 0020-1693
- DOI
- 10.1016/S0020-1693(01)00396-6
- language
- English
- LU publication?
- yes
- id
- 78d4525c-edc3-4233-8f3c-ac4fae8728ab
- date added to LUP
- 2019-05-03 15:11:47
- date last changed
- 2022-02-14 09:22:51
@article{78d4525c-edc3-4233-8f3c-ac4fae8728ab, abstract = {{<p>The reaction between trans-PtPhCl(SMe<sub>2</sub>)<sub>2</sub> and (R,R)-CHIRAPHOS gives cis-[PtPhCl((R,R)-CHIRAPHOS)] (1). The crystals of which are monoclinic, space group P2<sub>1</sub> with a = 12.875(3), b = 18.012(4), c = 13.864(3) Å, β = 109.71(3)° and Z = 4. In CDCl<sub>3</sub> 1 reacts with Ph<sub>2</sub>P(C<sub>6</sub>H<sub>4</sub>)CH<sub>2</sub>N(Me)(COEt) to give cis[PtCl<sub>2</sub>((R,R)-CHIRAPHOS)] (2), the crystals of which are monoclinic, space group P2<sub>1</sub> with a = 7.8052(16), b = 17.679(4), c = 9.843(2) Å, β = 100.67(3)° and Z = 2.</p>}}, author = {{Johansson, Maria H. and Malmström, Torsten and Wendt, Ola F.}}, issn = {{0020-1693}}, keywords = {{Chiral phosphine complexes; Crystal structures; Platinum complexes}}, language = {{eng}}, month = {{05}}, number = {{1-2}}, pages = {{149--152}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{Chiral platinum(II) complexes. Crystal and molecular structures of cis-[PtPhCl((R,R)-CHIRAPHOS)] and cis-[PtCl<sub>2</sub>((R,R)-CHIRAPHOS)]}}, url = {{http://dx.doi.org/10.1016/S0020-1693(01)00396-6}}, doi = {{10.1016/S0020-1693(01)00396-6}}, volume = {{316}}, year = {{2001}}, }