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Processing nanomaterials in molten salts : Partially electrometallized TiO2 as Pt support for enhanced catalytic oxidation of CO and CH3OH

Shi, Xianxing ; Jin, Xianbo ; Xiao, Wei ; Hou, Xu LU orcid ; Chen, Hualin and Chen, George Zheng (2011) In Chemistry - A European Journal 17(31). p.8562-8567
Abstract

Facilitated CO stripping: Partial metallization of TiO2 nanoparticles (NPs) by electroreduction in the molten, eutectic mixture of CaCl2 and NaCl at 600 °C produces nano- and submicro-sized Ti2O and CaδTiOx (perovskites, x/× δ 2) that can significantly promote the catalytic activity of Pt NPs towards the oxidation of CO and CH3OH in acidic solutions

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author
; ; ; ; and
publishing date
type
Contribution to journal
publication status
published
keywords
electrocatalysis, electrochemistry, methanol oxidation, molten salts, platinum, titanium
in
Chemistry - A European Journal
volume
17
issue
31
pages
6 pages
publisher
Wiley-Blackwell
external identifiers
  • scopus:79960550334
ISSN
0947-6539
DOI
10.1002/chem.201100410
language
English
LU publication?
no
id
7988ef6b-9352-4906-bdad-d11e4006e708
date added to LUP
2025-12-05 22:43:51
date last changed
2025-12-12 13:00:00
@article{7988ef6b-9352-4906-bdad-d11e4006e708,
  abstract     = {{<p>Facilitated CO stripping: Partial metallization of TiO<sub>2</sub> nanoparticles (NPs) by electroreduction in the molten, eutectic mixture of CaCl<sub>2</sub> and NaCl at 600 °C produces nano- and submicro-sized Ti<sub>2</sub>O and Ca<sub>δ</sub>TiO<sub>x</sub> (perovskites, x/× δ 2) that can significantly promote the catalytic activity of Pt NPs towards the oxidation of CO and CH<sub>3</sub>OH in acidic solutions</p>}},
  author       = {{Shi, Xianxing and Jin, Xianbo and Xiao, Wei and Hou, Xu and Chen, Hualin and Chen, George Zheng}},
  issn         = {{0947-6539}},
  keywords     = {{electrocatalysis; electrochemistry; methanol oxidation; molten salts; platinum; titanium}},
  language     = {{eng}},
  month        = {{07}},
  number       = {{31}},
  pages        = {{8562--8567}},
  publisher    = {{Wiley-Blackwell}},
  series       = {{Chemistry - A European Journal}},
  title        = {{Processing nanomaterials in molten salts : Partially electrometallized TiO<sub>2</sub> as Pt support for enhanced catalytic oxidation of CO and CH<sub>3</sub>OH}},
  url          = {{http://dx.doi.org/10.1002/chem.201100410}},
  doi          = {{10.1002/chem.201100410}},
  volume       = {{17}},
  year         = {{2011}},
}