Sulfonated poly(arylene ether sulfone) ionomers containing di- and tetrasulfonated arylene sulfone segments
Persson Jutemar, Elin LU ; Takamuku, Shogo LU and Jannasch, Patric LU
(2011)
In Polymer Chemistry
2(1).
p.181-191
- Abstract
- Poly(arylene ether sulfone) (PSU) ionomers containing disulfonated aryl-SO2-aryl and tetrasulfonated aryl-SO2-aryl-aryl-SO2-aryl segments, respectively, were synthesized and studied to establish their structure–property relationships as proton-exchange membranes. High molecular weight PSUs with different distributions of sulfone bridges in the backbone were prepared by nucleophilic aromatic substitution reactions involving 4,4′-dichlorodiphenyl sulfone (DCDPS), 4,4′-bis[(4-chlorophenyl)sulfonyl]-1,1′-biphenyl (BCPSB), 4,4′-isopropylidenediphenol (bisphenol A), and 4,4′-(1,4-phenylenediisopropylidene)bisphenol (bisphenol P). The polymers were sulfonated via metallation and reaction with sulfur dioxide, followed by oxidation of the resulting... (More)
- Poly(arylene ether sulfone) (PSU) ionomers containing disulfonated aryl-SO2-aryl and tetrasulfonated aryl-SO2-aryl-aryl-SO2-aryl segments, respectively, were synthesized and studied to establish their structure–property relationships as proton-exchange membranes. High molecular weight PSUs with different distributions of sulfone bridges in the backbone were prepared by nucleophilic aromatic substitution reactions involving 4,4′-dichlorodiphenyl sulfone (DCDPS), 4,4′-bis[(4-chlorophenyl)sulfonyl]-1,1′-biphenyl (BCPSB), 4,4′-isopropylidenediphenol (bisphenol A), and 4,4′-(1,4-phenylenediisopropylidene)bisphenol (bisphenol P). The polymers were sulfonated via metallation and reaction with sulfur dioxide, followed by oxidation of the resulting sulfinates. This procedure allowed the introduction of two sulfonic acid units on electron-deficient aryl rings in ortho positions to each sulfone bridge of the PSUs. Analysis by small angle X-ray scattering of solvent cast membranes showed that ionic clustering was promoted in ionomers containing sulfonated BCPSB residues and flexible bisphenol P residues. The fully sulfonated PSUs had ion-exchange capacities (IECs) of 3.3–4.1 meq g−1 and were water soluble. However, partly sulfonated polymers with IECs of approx. 1.7 meq g−1 showed high proton conductivity at moderate water uptake and decomposed only above 240 °C during heating 1 °C min−1 under air. This work demonstrated that BCPSB residues can be conveniently and fully tetrasulfonated, which opens possibilities to prepare various aromatic copolymers and membranes with locally very high densities of hydrolytically stable sulfonic acid groups. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1712075
- author
- Persson Jutemar, Elin
LU
; Takamuku, Shogo
LU
and Jannasch, Patric
LU
- organization
- publishing date
- 2011
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- sulfonation, proton conductivity, polymer electrolytes, proton exchange membrane fuel cells, SAXS
- in
- Polymer Chemistry
- volume
- 2
- issue
- 1
- pages
- 181 - 191
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000285066700022
- scopus:78650104494
- ISSN
- 1759-9954
- DOI
- 10.1039/C0PY00290A
- language
- English
- LU publication?
- yes
- additional info
- published on the web 2nd November 2010 The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)
- id
- 7edd2a6b-ed4c-4181-b4a9-b06a1486724f (old id 1712075)
- alternative location
- http://pubs.rsc.org/en/Content/ArticleLanding/2011/PY/C0PY00290A
- date added to LUP
- 2016-04-01 10:21:25
- date last changed
- 2022-03-19 19:58:39
@article{7edd2a6b-ed4c-4181-b4a9-b06a1486724f,
abstract = {{Poly(arylene ether sulfone) (PSU) ionomers containing disulfonated aryl-SO2-aryl and tetrasulfonated aryl-SO2-aryl-aryl-SO2-aryl segments, respectively, were synthesized and studied to establish their structure–property relationships as proton-exchange membranes. High molecular weight PSUs with different distributions of sulfone bridges in the backbone were prepared by nucleophilic aromatic substitution reactions involving 4,4′-dichlorodiphenyl sulfone (DCDPS), 4,4′-bis[(4-chlorophenyl)sulfonyl]-1,1′-biphenyl (BCPSB), 4,4′-isopropylidenediphenol (bisphenol A), and 4,4′-(1,4-phenylenediisopropylidene)bisphenol (bisphenol P). The polymers were sulfonated via metallation and reaction with sulfur dioxide, followed by oxidation of the resulting sulfinates. This procedure allowed the introduction of two sulfonic acid units on electron-deficient aryl rings in ortho positions to each sulfone bridge of the PSUs. Analysis by small angle X-ray scattering of solvent cast membranes showed that ionic clustering was promoted in ionomers containing sulfonated BCPSB residues and flexible bisphenol P residues. The fully sulfonated PSUs had ion-exchange capacities (IECs) of 3.3–4.1 meq g−1 and were water soluble. However, partly sulfonated polymers with IECs of approx. 1.7 meq g−1 showed high proton conductivity at moderate water uptake and decomposed only above 240 °C during heating 1 °C min−1 under air. This work demonstrated that BCPSB residues can be conveniently and fully tetrasulfonated, which opens possibilities to prepare various aromatic copolymers and membranes with locally very high densities of hydrolytically stable sulfonic acid groups.}},
author = {{Persson Jutemar, Elin and Takamuku, Shogo and Jannasch, Patric}},
issn = {{1759-9954}},
keywords = {{sulfonation; proton conductivity; polymer electrolytes; proton exchange membrane fuel cells; SAXS}},
language = {{eng}},
number = {{1}},
pages = {{181--191}},
publisher = {{Royal Society of Chemistry}},
series = {{Polymer Chemistry}},
title = {{Sulfonated poly(arylene ether sulfone) ionomers containing di- and tetrasulfonated arylene sulfone segments}},
url = {{http://dx.doi.org/10.1039/C0PY00290A}},
doi = {{10.1039/C0PY00290A}},
volume = {{2}},
year = {{2011}},
}