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Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).

Kondrashov, Mikhail LU ; Fleckhaus, André LU ; Gritcenko, Roman and Wendt, Ola LU (2015) In Acta crystallographica. Section E, Crystallographic communications 71(Pt 9). p.166-166
Abstract
The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Acta crystallographica. Section E, Crystallographic communications
volume
71
issue
Pt 9
pages
166 - 166
publisher
International Union of Crystallography
external identifiers
  • PMID:26396868
  • Scopus:84953870386
  • WOS:000370079100007
ISSN
2056-9890
DOI
10.1107/S2056989015015005
language
English
LU publication?
yes
id
9ae8a29a-dbd4-49ff-afca-b9169086938e (old id 8035172)
date added to LUP
2015-10-30 13:12:02
date last changed
2017-01-01 07:43:23
@article{9ae8a29a-dbd4-49ff-afca-b9169086938e,
  abstract     = {The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.},
  author       = {Kondrashov, Mikhail and Fleckhaus, André and Gritcenko, Roman and Wendt, Ola},
  issn         = {2056-9890},
  language     = {eng},
  number       = {Pt 9},
  pages        = {166--166},
  publisher    = {International Union of Crystallography},
  series       = {Acta crystallographica. Section E, Crystallographic communications},
  title        = {Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).},
  url          = {http://dx.doi.org/10.1107/S2056989015015005},
  volume       = {71},
  year         = {2015},
}