Equation of state of PEG/PEO in good solvent. Comparison between a one-parameter EOS and experiments
Li, Joaquim LU ; Turesson, Martin LU ; Anderberg Haglund, Caroline LU ; Cabane, Bernard and Skepö, Marie LU
(2015)
In Polymer
80.
p.205-213
- Abstract
- We investigate, through osmotic pressure measurements, the validity of the single-parameter equation of state (EOS) for solutions of polyethylene glycols in water, by Cohen et al.(1,2) We show that it is physically meaningful and that a reasonable good correspondence between the osmotic pressures for PEG35 in large range of concentrations is obtained. We also take the chain length dependence into account in our analysis, as suggested by Cohen et al. By recalculating the experimental pressures in the paper by Jonsson et al. 3 applying the new calibration curve, which is based on the experimental results obtained in this study and the EOS obtained by Cohen et al., there is almost a perfect correspondence between the simulations and the... (More)
- We investigate, through osmotic pressure measurements, the validity of the single-parameter equation of state (EOS) for solutions of polyethylene glycols in water, by Cohen et al.(1,2) We show that it is physically meaningful and that a reasonable good correspondence between the osmotic pressures for PEG35 in large range of concentrations is obtained. We also take the chain length dependence into account in our analysis, as suggested by Cohen et al. By recalculating the experimental pressures in the paper by Jonsson et al. 3 applying the new calibration curve, which is based on the experimental results obtained in this study and the EOS obtained by Cohen et al., there is almost a perfect correspondence between the simulations and the experiments. These results have implications for correctly probing macromolecular interactions in wide range of systems when applying the osmotic stress method. (C) 2015 Elsevier Ltd. All rights reserved. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/8560207
- author
- Li, Joaquim
LU
; Turesson, Martin
LU
; Anderberg Haglund, Caroline
LU
; Cabane, Bernard
and Skepö, Marie
LU
- organization
- publishing date
- 2015
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- PEG/PEO, Equation of state, Osmotic pressure, Scaling function
- in
- Polymer
- volume
- 80
- pages
- 205 - 213
- publisher
- Elsevier
- external identifiers
-
- wos:000365813500023
- scopus:84946574550
- ISSN
- 0032-3861
- DOI
- 10.1016/j.polymer.2015.10.056
- language
- English
- LU publication?
- yes
- id
- a2f97e66-e718-43e8-ae8c-b47e8b65919e (old id 8560207)
- date added to LUP
- 2016-04-01 12:52:37
- date last changed
- 2024-10-09 18:18:24
@article{a2f97e66-e718-43e8-ae8c-b47e8b65919e,
abstract = {{We investigate, through osmotic pressure measurements, the validity of the single-parameter equation of state (EOS) for solutions of polyethylene glycols in water, by Cohen et al.(1,2) We show that it is physically meaningful and that a reasonable good correspondence between the osmotic pressures for PEG35 in large range of concentrations is obtained. We also take the chain length dependence into account in our analysis, as suggested by Cohen et al. By recalculating the experimental pressures in the paper by Jonsson et al. 3 applying the new calibration curve, which is based on the experimental results obtained in this study and the EOS obtained by Cohen et al., there is almost a perfect correspondence between the simulations and the experiments. These results have implications for correctly probing macromolecular interactions in wide range of systems when applying the osmotic stress method. (C) 2015 Elsevier Ltd. All rights reserved.}},
author = {{Li, Joaquim and Turesson, Martin and Anderberg Haglund, Caroline and Cabane, Bernard and Skepö, Marie}},
issn = {{0032-3861}},
keywords = {{PEG/PEO; Equation of state; Osmotic pressure; Scaling function}},
language = {{eng}},
pages = {{205--213}},
publisher = {{Elsevier}},
series = {{Polymer}},
title = {{Equation of state of PEG/PEO in good solvent. Comparison between a one-parameter EOS and experiments}},
url = {{http://dx.doi.org/10.1016/j.polymer.2015.10.056}},
doi = {{10.1016/j.polymer.2015.10.056}},
volume = {{80}},
year = {{2015}},
}