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High-Quality Metal-Organic Framework Ultrathin Films for Electronically Active Interfaces.

Rubio-Giménez, Víctor; Tatay, Sergio; Volatron, Florence; Martinez, Francisco LU ; Martí-Gastaldo, Carlos and Coronado, Eugenio (2016) In Journal of the American Chemical Society 138(8). p.2576-2584
Abstract
Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that this strategy might be useful for the integration... (More)
Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that this strategy might be useful for the integration of MOFs as active interfaces in electronic devices. (Less)
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of the American Chemical Society
volume
138
issue
8
pages
2576 - 2584
publisher
The American Chemical Society
external identifiers
  • pmid:26847507
  • scopus:84959573031
  • wos:000371453700028
ISSN
1520-5126
DOI
10.1021/jacs.5b09784
language
English
LU publication?
yes
id
d76f57c0-4a7f-4b1e-a87c-9830d9dbce49 (old id 8829244)
date added to LUP
2016-03-04 09:41:06
date last changed
2017-10-22 04:12:41
@article{d76f57c0-4a7f-4b1e-a87c-9830d9dbce49,
  abstract     = {Currently available methodologies arguably lack the exquisite control required for producing metal-organic framework (MOF) thin films of sufficient quality for electronic applications. By directing MOF transfer with self-assembled monolayers (SAMs), we achieve very smooth, homogeneous, highly oriented, ultrathin films across millimeter-scale areas that display moderate conductivity likely due to electron hopping. Here, the SAM is key for directing the transfer thereby enlarging the number and nature of the substrates of choice. We have exploited this versatility to evolve from deposition onto standard Si and Au to nonconventional substrates such as ferromagnetic Permalloy. We believe that this strategy might be useful for the integration of MOFs as active interfaces in electronic devices.},
  author       = {Rubio-Giménez, Víctor and Tatay, Sergio and Volatron, Florence and Martinez, Francisco and Martí-Gastaldo, Carlos and Coronado, Eugenio},
  issn         = {1520-5126},
  language     = {eng},
  month        = {02},
  number       = {8},
  pages        = {2576--2584},
  publisher    = {The American Chemical Society},
  series       = {Journal of the American Chemical Society},
  title        = {High-Quality Metal-Organic Framework Ultrathin Films for Electronically Active Interfaces.},
  url          = {http://dx.doi.org/10.1021/jacs.5b09784},
  volume       = {138},
  year         = {2016},
}