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Intrinsic viscosity of dispersions of core shell-particles

Zackrisson Oskolkova, Malin LU and Bergenholtz, Johan (2003) In Colloids and Surfaces A: Physicochemical and Engineering Aspects 225(1-3). p.119-127
Abstract
An analytic solution of the Brinkman and Stokes equations for a rigid sphere surrounded by a porous shell in pure

straining flow is presented. The solution permits for an analytic determination of the intrinsic viscosity in the dilutelimiting

expansion for the steady shear viscosity. The porous layer, characterized by a thickness and a constant

permeability, alters the intrinsic viscosity from the Einstein value. A hydrodynamic layer thickness based on the

intrinsic viscosity exhibits only a tenuous connection to the actual layer thickness within the present model. Together

with the analytical solution for the translational diffusion coefficient, derived previously by Masliyah and... (More)
An analytic solution of the Brinkman and Stokes equations for a rigid sphere surrounded by a porous shell in pure

straining flow is presented. The solution permits for an analytic determination of the intrinsic viscosity in the dilutelimiting

expansion for the steady shear viscosity. The porous layer, characterized by a thickness and a constant

permeability, alters the intrinsic viscosity from the Einstein value. A hydrodynamic layer thickness based on the

intrinsic viscosity exhibits only a tenuous connection to the actual layer thickness within the present model. Together

with the analytical solution for the translational diffusion coefficient, derived previously by Masliyah and co-workers,

the present solution allows for a more detailed characterization of polymerically stabilized particles than the commonly

used effective hard-sphere model (Less)
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author
and
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Colloidal dispersions, Core-shell, Intrinsic viscosity, Brinkman equation, Stokes flow
categories
Higher Education
in
Colloids and Surfaces A: Physicochemical and Engineering Aspects
volume
225
issue
1-3
pages
119 - 127
publisher
Elsevier
external identifiers
  • scopus:0042195121
ISSN
0927-7757
DOI
10.1016/S0927-7757(03)00323-6
language
English
LU publication?
no
id
907bd32b-687f-4da1-bda9-037e5150df58 (old id 3363681)
date added to LUP
2016-04-01 15:32:45
date last changed
2022-01-28 05:54:29
@article{907bd32b-687f-4da1-bda9-037e5150df58,
  abstract     = {{An analytic solution of the Brinkman and Stokes equations for a rigid sphere surrounded by a porous shell in pure<br/><br>
straining flow is presented. The solution permits for an analytic determination of the intrinsic viscosity in the dilutelimiting<br/><br>
expansion for the steady shear viscosity. The porous layer, characterized by a thickness and a constant<br/><br>
permeability, alters the intrinsic viscosity from the Einstein value. A hydrodynamic layer thickness based on the<br/><br>
intrinsic viscosity exhibits only a tenuous connection to the actual layer thickness within the present model. Together<br/><br>
with the analytical solution for the translational diffusion coefficient, derived previously by Masliyah and co-workers,<br/><br>
the present solution allows for a more detailed characterization of polymerically stabilized particles than the commonly<br/><br>
used effective hard-sphere model}},
  author       = {{Zackrisson Oskolkova, Malin and Bergenholtz, Johan}},
  issn         = {{0927-7757}},
  keywords     = {{Colloidal dispersions; Core-shell; Intrinsic viscosity; Brinkman equation; Stokes flow}},
  language     = {{eng}},
  number       = {{1-3}},
  pages        = {{119--127}},
  publisher    = {{Elsevier}},
  series       = {{Colloids and Surfaces A: Physicochemical and Engineering Aspects}},
  title        = {{Intrinsic viscosity of dispersions of core shell-particles}},
  url          = {{http://dx.doi.org/10.1016/S0927-7757(03)00323-6}},
  doi          = {{10.1016/S0927-7757(03)00323-6}},
  volume       = {{225}},
  year         = {{2003}},
}