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Synthesis, characterization and reactivity of tetranuclear ruthenium hydrido clusters containing chiral phosphine ligands

Moberg, Viktor LU ; Homanen, Pertti LU ; Selva, S ; Persson, Roger LU ; Haukka, M ; Pakkanen, TA ; Monari, M and Nordlander, Ebbe LU (2006) In Dalton Transactions p.279-288
Abstract
The chiral clusters [H4Ru4(CO)(12-n)(L)(n)] (n = 1, 2; L = NMDPP), 1,1-[H4Ru4(CO)(10)(L - L)] (L - L = DUPHOS, DIPAMP), 1,2-[H4Ru4(CO)(10)(DIOP)] and [{H4Ru4(CO)(10)(DIOP)}(2)] have been synthesized by derivatizing the parent carbonyl cluster [H4Ru4(CO)(12)] with the appropriate mono- or didentate chiral phosphine ligand. The phosphine-substituted clusters were found to be able to catalyze the ( asymmetric) hydrogenation of tiglic acid albeit with relatively low selectivity (enantiomeric excesses varying from 0 to 23%). It was found that the stability of the chiral ruthenium hydride clusters and the product distribution obtained in the catalytic reactions are dependent on the nature of the chiral phosphine. The crystal structures of... (More)
The chiral clusters [H4Ru4(CO)(12-n)(L)(n)] (n = 1, 2; L = NMDPP), 1,1-[H4Ru4(CO)(10)(L - L)] (L - L = DUPHOS, DIPAMP), 1,2-[H4Ru4(CO)(10)(DIOP)] and [{H4Ru4(CO)(10)(DIOP)}(2)] have been synthesized by derivatizing the parent carbonyl cluster [H4Ru4(CO)(12)] with the appropriate mono- or didentate chiral phosphine ligand. The phosphine-substituted clusters were found to be able to catalyze the ( asymmetric) hydrogenation of tiglic acid albeit with relatively low selectivity (enantiomeric excesses varying from 0 to 23%). It was found that the stability of the chiral ruthenium hydride clusters and the product distribution obtained in the catalytic reactions are dependent on the nature of the chiral phosphine. The crystal structures of [H4Ru4(CO)(12-n)(L)(n)] (n = 1, 2; L = NMDPP), 1,1-[H4Ru4(CO)(10)(L-L)] (L - L = DUPHOS, O-DUPHOS ( partially oxygenated ligand), DIPAMP), 1,2-[H4Ru4(CO)(10)(DIOP)] and [{H4Ru4(CO)(10)(DIOP)}(2)] are presented. (Less)
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Dalton Transactions
issue
1
pages
279 - 288
publisher
Royal Society of Chemistry
external identifiers
  • wos:000233968200032
  • scopus:33645509135
ISSN
1477-9234
DOI
10.1039/b515273a
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060), Inorganic chemistry (ceased) (LUR000010)
id
92001678-31ab-4abd-bccb-0fe8519e54f6 (old id 421768)
date added to LUP
2016-04-01 11:51:23
date last changed
2022-01-26 19:14:50
@article{92001678-31ab-4abd-bccb-0fe8519e54f6,
  abstract     = {{The chiral clusters [H4Ru4(CO)(12-n)(L)(n)] (n = 1, 2; L = NMDPP), 1,1-[H4Ru4(CO)(10)(L - L)] (L - L = DUPHOS, DIPAMP), 1,2-[H4Ru4(CO)(10)(DIOP)] and [{H4Ru4(CO)(10)(DIOP)}(2)] have been synthesized by derivatizing the parent carbonyl cluster [H4Ru4(CO)(12)] with the appropriate mono- or didentate chiral phosphine ligand. The phosphine-substituted clusters were found to be able to catalyze the ( asymmetric) hydrogenation of tiglic acid albeit with relatively low selectivity (enantiomeric excesses varying from 0 to 23%). It was found that the stability of the chiral ruthenium hydride clusters and the product distribution obtained in the catalytic reactions are dependent on the nature of the chiral phosphine. The crystal structures of [H4Ru4(CO)(12-n)(L)(n)] (n = 1, 2; L = NMDPP), 1,1-[H4Ru4(CO)(10)(L-L)] (L - L = DUPHOS, O-DUPHOS ( partially oxygenated ligand), DIPAMP), 1,2-[H4Ru4(CO)(10)(DIOP)] and [{H4Ru4(CO)(10)(DIOP)}(2)] are presented.}},
  author       = {{Moberg, Viktor and Homanen, Pertti and Selva, S and Persson, Roger and Haukka, M and Pakkanen, TA and Monari, M and Nordlander, Ebbe}},
  issn         = {{1477-9234}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{279--288}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Dalton Transactions}},
  title        = {{Synthesis, characterization and reactivity of tetranuclear ruthenium hydrido clusters containing chiral phosphine ligands}},
  url          = {{http://dx.doi.org/10.1039/b515273a}},
  doi          = {{10.1039/b515273a}},
  year         = {{2006}},
}