Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers
(2021) In Polymer Chemistry 12(41). p.5937-5941- Abstract
- A series of regioisomeric isosorbide mono-epoxides, as well as diastereomerically pure mono-epoxy derivatives, have been prepared and studied. Anionic ring-opening polymerization of methoxy-capped monomers produced linear polyethers tethered with isosorbide units. These reasonably high molecular weight polymers exhibited glass transition temperatures at around 10-15 °C and thermal stability up to approximately 300 °C, which indicated that the mono-epoxides are promising building blocks for well-defined biobased polymers.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/92749054-26fc-44aa-a335-5ff997da0902
- author
- Matt, Livia ; Liblikas, Ilme ; Bonjour, Olivier LU ; Jannasch, Patric LU and Vares, Lauri
- organization
- publishing date
- 2021
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Polymer Chemistry
- volume
- 12
- issue
- 41
- pages
- 5 pages
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:85118297934
- ISSN
- 1759-9954
- DOI
- 10.1039/D1PY00687H
- language
- English
- LU publication?
- yes
- additional info
- Published 12 Oct 2021
- id
- 92749054-26fc-44aa-a335-5ff997da0902
- date added to LUP
- 2021-05-13 18:24:14
- date last changed
- 2022-04-27 01:57:59
@article{92749054-26fc-44aa-a335-5ff997da0902, abstract = {{A series of regioisomeric isosorbide mono-epoxides, as well as diastereomerically pure mono-epoxy derivatives, have been prepared and studied. Anionic ring-opening polymerization of methoxy-capped monomers produced linear polyethers tethered with isosorbide units. These reasonably high molecular weight polymers exhibited glass transition temperatures at around 10-15 °C and thermal stability up to approximately 300 °C, which indicated that the mono-epoxides are promising building blocks for well-defined biobased polymers.}}, author = {{Matt, Livia and Liblikas, Ilme and Bonjour, Olivier and Jannasch, Patric and Vares, Lauri}}, issn = {{1759-9954}}, language = {{eng}}, number = {{41}}, pages = {{5937--5941}}, publisher = {{Royal Society of Chemistry}}, series = {{Polymer Chemistry}}, title = {{Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers}}, url = {{http://dx.doi.org/10.1039/D1PY00687H}}, doi = {{10.1039/D1PY00687H}}, volume = {{12}}, year = {{2021}}, }