Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers

Matt, Livia ; Liblikas, Ilme ; Bonjour, Olivier LU ; Jannasch, Patric LU orcid and Vares, Lauri (2021) In Polymer Chemistry 12(41). p.5937-5941
Abstract
A series of regioisomeric isosorbide mono-epoxides, as well as diastereomerically pure mono-epoxy derivatives, have been prepared and studied. Anionic ring-opening polymerization of methoxy-capped monomers produced linear polyethers tethered with isosorbide units. These reasonably high molecular weight polymers exhibited glass transition temperatures at around 10-15 °C and thermal stability up to approximately 300 °C, which indicated that the mono-epoxides are promising building blocks for well-defined biobased polymers.
Please use this url to cite or link to this publication:
author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Polymer Chemistry
volume
12
issue
41
pages
5 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:85118297934
ISSN
1759-9954
DOI
10.1039/D1PY00687H
language
English
LU publication?
yes
additional info
Published 12 Oct 2021
id
92749054-26fc-44aa-a335-5ff997da0902
date added to LUP
2021-05-13 18:24:14
date last changed
2022-04-27 01:57:59
@article{92749054-26fc-44aa-a335-5ff997da0902,
  abstract     = {{A series of regioisomeric isosorbide mono-epoxides, as well as diastereomerically pure mono-epoxy derivatives, have been prepared and studied. Anionic ring-opening polymerization of methoxy-capped monomers produced linear polyethers tethered with isosorbide units. These reasonably high molecular weight polymers exhibited glass transition temperatures at around 10-15 °C and thermal stability up to approximately 300 °C, which indicated that the mono-epoxides are promising building blocks for well-defined biobased polymers.}},
  author       = {{Matt, Livia and Liblikas, Ilme and Bonjour, Olivier and Jannasch, Patric and Vares, Lauri}},
  issn         = {{1759-9954}},
  language     = {{eng}},
  number       = {{41}},
  pages        = {{5937--5941}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Polymer Chemistry}},
  title        = {{Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers}},
  url          = {{http://dx.doi.org/10.1039/D1PY00687H}},
  doi          = {{10.1039/D1PY00687H}},
  volume       = {{12}},
  year         = {{2021}},
}