Diffusion of a mixture of cations and anions dissolved in water
(1999) In Cement and Concrete Research 29(8). p.1261-1270- Abstract
- In service life modeling of concrete, the ion transport in the pore solution is crucial. The main deterioration phenomena associated
with ions in the pore solution are (1) corrosion due to external chloride ions reaching the embedded reinforcement bars; (2) carbonation
due to presence of dissolved carbon dioxide (which will form carbonic acid with water) supplied from the surrounding air; and (3) leaching
of hydroxide ions from the pore solution to the surrounding environment. Models dealing with diffusion of ions are usually based on
the mass balance equations for the individual diffusing ions together with constitutive relations for the mass density flows and for the mass
exchange among the... (More) - In service life modeling of concrete, the ion transport in the pore solution is crucial. The main deterioration phenomena associated
with ions in the pore solution are (1) corrosion due to external chloride ions reaching the embedded reinforcement bars; (2) carbonation
due to presence of dissolved carbon dioxide (which will form carbonic acid with water) supplied from the surrounding air; and (3) leaching
of hydroxide ions from the pore solution to the surrounding environment. Models dealing with diffusion of ions are usually based on
the mass balance equations for the individual diffusing ions together with constitutive relations for the mass density flows and for the mass
exchange among the constituents. The important consequences of electroneutrality among the diffusing ions, however, is often omitted in
models dealing with diffusion of ions in the pore solution of concrete. Here a method will be examined that allows diffusion of different
ions in water, which satisfies both the electroneutrality requirement and the mass balance laws. For simplicity the effect of built-up electric
double layers on the charged pore walls will not be treated. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/1528089
- author
- Johannesson, Björn LU
- organization
- publishing date
- 1999
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- Diffusion, Carbonation, Leaching, Pore solution, Surface layer
- in
- Cement and Concrete Research
- volume
- 29
- issue
- 8
- pages
- 1261 - 1270
- publisher
- Elsevier
- external identifiers
-
- scopus:0032684548
- ISSN
- 0008-8846
- DOI
- 10.1016/S0008-8846(99)00114-3
- language
- English
- LU publication?
- yes
- id
- 92936d90-8c74-4376-89fd-30b12bd0ea72 (old id 1528089)
- date added to LUP
- 2016-04-01 15:39:24
- date last changed
- 2022-01-28 06:27:29
@article{92936d90-8c74-4376-89fd-30b12bd0ea72,
abstract = {{In service life modeling of concrete, the ion transport in the pore solution is crucial. The main deterioration phenomena associated<br/><br>
with ions in the pore solution are (1) corrosion due to external chloride ions reaching the embedded reinforcement bars; (2) carbonation<br/><br>
due to presence of dissolved carbon dioxide (which will form carbonic acid with water) supplied from the surrounding air; and (3) leaching<br/><br>
of hydroxide ions from the pore solution to the surrounding environment. Models dealing with diffusion of ions are usually based on<br/><br>
the mass balance equations for the individual diffusing ions together with constitutive relations for the mass density flows and for the mass<br/><br>
exchange among the constituents. The important consequences of electroneutrality among the diffusing ions, however, is often omitted in<br/><br>
models dealing with diffusion of ions in the pore solution of concrete. Here a method will be examined that allows diffusion of different<br/><br>
ions in water, which satisfies both the electroneutrality requirement and the mass balance laws. For simplicity the effect of built-up electric<br/><br>
double layers on the charged pore walls will not be treated.}},
author = {{Johannesson, Björn}},
issn = {{0008-8846}},
keywords = {{Diffusion; Carbonation; Leaching; Pore solution; Surface layer}},
language = {{eng}},
number = {{8}},
pages = {{1261--1270}},
publisher = {{Elsevier}},
series = {{Cement and Concrete Research}},
title = {{Diffusion of a mixture of cations and anions dissolved in water}},
url = {{http://dx.doi.org/10.1016/S0008-8846(99)00114-3}},
doi = {{10.1016/S0008-8846(99)00114-3}},
volume = {{29}},
year = {{1999}},
}