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cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

Hansson, Christian LU and Oskarsson, Åke LU (2008) In Acta Crystallographica. Section C: Crystal Structure Communications 64. p.61-63
Abstract
The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).
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author
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
platinum compounds, data mining, crystallography
in
Acta Crystallographica. Section C: Crystal Structure Communications
volume
64
pages
61 - 63
publisher
International Union of Crystallography
external identifiers
  • wos:000252881500022
  • scopus:38749151929
  • pmid:18216443
ISSN
0108-2701
DOI
10.1107/S0108270107061902
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
4c686120-e45c-40b2-b2bb-9d3b6b2b9c22 (old id 941912)
date added to LUP
2016-04-01 13:05:08
date last changed
2025-04-04 14:27:09
@article{4c686120-e45c-40b2-b2bb-9d3b6b2b9c22,
  abstract     = {{The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).}},
  author       = {{Hansson, Christian and Oskarsson, Åke}},
  issn         = {{0108-2701}},
  keywords     = {{platinum compounds; data mining; crystallography}},
  language     = {{eng}},
  pages        = {{61--63}},
  publisher    = {{International Union of Crystallography}},
  series       = {{Acta Crystallographica. Section C: Crystal Structure Communications}},
  title        = {{cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)}},
  url          = {{http://dx.doi.org/10.1107/S0108270107061902}},
  doi          = {{10.1107/S0108270107061902}},
  volume       = {{64}},
  year         = {{2008}},
}