Synthesis and Characterization of Iron(III) Complexes of a New Ligand Containing a Potentially Bridging Carboxylate; Structural Characterization of Helical Tetranuclear Iron Complex
(1999) In Chemical Communications p.1193-1194- Abstract
- Reaction of the new polydentate ligand 2,6-bis{3-[N,N-di(2-pyridylmethyl)amino]propoxy}benzoic acid (LH) with Fe(ClO4)3 followed by addition of chloroacetic acid leads to the formation of the tetranuclear complex [{Fe2OL(ClCH2- CO2)2}2](ClO4)4, the crystal structure of which reveals that it consists of two FeII2(µ-O)(µ-RCO2)2 cores that are linked via the two L ligands in a helical structure, with the carboxylate moieties of the two ligands forming a hydrogen-bonded pair at the center of the helix.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/959758
- author
- Trukhan, Vladimir M ; Pierpont, Cortlandt G ; Nordlander, Ebbe LU and Shteinman, Albert A
- organization
- publishing date
- 1999
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Chemical Communications
- issue
- 13
- pages
- 1193 - 1194
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:0033532862
- ISSN
- 1364-548X
- DOI
- 10.1039/a809888c
- language
- English
- LU publication?
- yes
- id
- 58e114e4-9e20-49f2-a650-af68b43379ce (old id 959758)
- date added to LUP
- 2016-04-01 12:02:49
- date last changed
- 2022-01-26 22:01:50
@article{58e114e4-9e20-49f2-a650-af68b43379ce, abstract = {{Reaction of the new polydentate ligand 2,6-bis{3-[N,N-di(2-pyridylmethyl)amino]propoxy}benzoic acid (LH) with Fe(ClO4)3 followed by addition of chloroacetic acid leads to the formation of the tetranuclear complex [{Fe2OL(ClCH2- CO2)2}2](ClO4)4, the crystal structure of which reveals that it consists of two FeII2(µ-O)(µ-RCO2)2 cores that are linked via the two L ligands in a helical structure, with the carboxylate moieties of the two ligands forming a hydrogen-bonded pair at the center of the helix.}}, author = {{Trukhan, Vladimir M and Pierpont, Cortlandt G and Nordlander, Ebbe and Shteinman, Albert A}}, issn = {{1364-548X}}, language = {{eng}}, number = {{13}}, pages = {{1193--1194}}, publisher = {{Royal Society of Chemistry}}, series = {{Chemical Communications}}, title = {{Synthesis and Characterization of Iron(III) Complexes of a New Ligand Containing a Potentially Bridging Carboxylate; Structural Characterization of Helical Tetranuclear Iron Complex}}, url = {{http://dx.doi.org/10.1039/a809888c}}, doi = {{10.1039/a809888c}}, year = {{1999}}, }