Ultrafast charge transfer and atomic orbital polarization
(2007) In Journal of Chemical Physics 127(17).- Abstract
- The role of orbital polarization for ultrafast charge transfer between an atomic adsorbate and a substrate is explored. Core hole clock spectroscopy with linearly polarized x-ray radiation allows to selectively excite adsorbate resonance states with defined spatial orientation relative to the substrate surface. For c(4x2)S/Ru(0001) the charge transfer times between the sulfur 2s(-1)3p(*+1) antibonding resonance and the ruthenium substrate have been studied, with the 2s electron excited into the 3p(perpendicular to)(*) state along the surface normal and the 3p(parallel to)(*) state in the surface plane. The charge transfer times are determined as 0.18 +/- 0.07 and 0.84 +/- 0.23 fs, respectively. This variation is the direct consequence of... (More)
- The role of orbital polarization for ultrafast charge transfer between an atomic adsorbate and a substrate is explored. Core hole clock spectroscopy with linearly polarized x-ray radiation allows to selectively excite adsorbate resonance states with defined spatial orientation relative to the substrate surface. For c(4x2)S/Ru(0001) the charge transfer times between the sulfur 2s(-1)3p(*+1) antibonding resonance and the ruthenium substrate have been studied, with the 2s electron excited into the 3p(perpendicular to)(*) state along the surface normal and the 3p(parallel to)(*) state in the surface plane. The charge transfer times are determined as 0.18 +/- 0.07 and 0.84 +/- 0.23 fs, respectively. This variation is the direct consequence of the different adsorbate-substrate orbital overlap. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/971884
- author
- Deppe, M. ; Foehlisch, A. ; Hennies, Franz LU ; Sanchez-Portal, D. ; Echenique, P. M. and Wurth, W.
- organization
- publishing date
- 2007
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Journal of Chemical Physics
- volume
- 127
- issue
- 17
- publisher
- American Institute of Physics (AIP)
- external identifiers
-
- wos:000250787300045
- scopus:35948999204
- ISSN
- 0021-9606
- DOI
- 10.1063/1.2781395
- language
- English
- LU publication?
- yes
- id
- 440d223f-f3ae-4506-8e9d-34779bdbea43 (old id 971884)
- date added to LUP
- 2016-04-01 12:06:29
- date last changed
- 2022-02-11 02:09:53
@article{440d223f-f3ae-4506-8e9d-34779bdbea43,
abstract = {{The role of orbital polarization for ultrafast charge transfer between an atomic adsorbate and a substrate is explored. Core hole clock spectroscopy with linearly polarized x-ray radiation allows to selectively excite adsorbate resonance states with defined spatial orientation relative to the substrate surface. For c(4x2)S/Ru(0001) the charge transfer times between the sulfur 2s(-1)3p(*+1) antibonding resonance and the ruthenium substrate have been studied, with the 2s electron excited into the 3p(perpendicular to)(*) state along the surface normal and the 3p(parallel to)(*) state in the surface plane. The charge transfer times are determined as 0.18 +/- 0.07 and 0.84 +/- 0.23 fs, respectively. This variation is the direct consequence of the different adsorbate-substrate orbital overlap.}},
author = {{Deppe, M. and Foehlisch, A. and Hennies, Franz and Sanchez-Portal, D. and Echenique, P. M. and Wurth, W.}},
issn = {{0021-9606}},
language = {{eng}},
number = {{17}},
publisher = {{American Institute of Physics (AIP)}},
series = {{Journal of Chemical Physics}},
title = {{Ultrafast charge transfer and atomic orbital polarization}},
url = {{http://dx.doi.org/10.1063/1.2781395}},
doi = {{10.1063/1.2781395}},
volume = {{127}},
year = {{2007}},
}