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A desymmetrization route to fused Troger's base analogues: Synthesis, isolation, and characterization of the first anti-anti diastereomer of a fused tris-Troger's base analogue

Hansson, Anna LU ; Wixe, Torbjörn ; Bergquist, Karl-Erik LU and Wärnmark, Kenneth LU (2005) In Organic Letters 7(10). p.2019-2022
Abstract
A desymmetrization route to fused Troger's base analogues was developed. In this way, the synthesis of the first example of an anti-anti diastereomer of a fused tris-Troger's base analogue was accomplished. The resulting compound 5b is a nonlinear symmetric regioisomer obtained from p-bromoaniline in 7% yield. The corresponding syn-anti diastereomer 5a was obtained in 4% yield.
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author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Organic Letters
volume
7
issue
10
pages
2019 - 2022
publisher
The American Chemical Society (ACS)
external identifiers
  • wos:000228984500034
  • pmid:15876044
  • scopus:19544384188
  • pmid:15876044
ISSN
1523-7052
DOI
10.1021/ol050513g
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)
id
97fdff39-2ef8-40a3-8849-50ad39f86e06 (old id 152404)
date added to LUP
2016-04-01 12:29:24
date last changed
2022-01-27 05:48:41
@article{97fdff39-2ef8-40a3-8849-50ad39f86e06,
  abstract     = {{A desymmetrization route to fused Troger's base analogues was developed. In this way, the synthesis of the first example of an anti-anti diastereomer of a fused tris-Troger's base analogue was accomplished. The resulting compound 5b is a nonlinear symmetric regioisomer obtained from p-bromoaniline in 7% yield. The corresponding syn-anti diastereomer 5a was obtained in 4% yield.}},
  author       = {{Hansson, Anna and Wixe, Torbjörn and Bergquist, Karl-Erik and Wärnmark, Kenneth}},
  issn         = {{1523-7052}},
  language     = {{eng}},
  number       = {{10}},
  pages        = {{2019--2022}},
  publisher    = {{The American Chemical Society (ACS)}},
  series       = {{Organic Letters}},
  title        = {{A desymmetrization route to fused Troger's base analogues: Synthesis, isolation, and characterization of the first anti-anti diastereomer of a fused tris-Troger's base analogue}},
  url          = {{http://dx.doi.org/10.1021/ol050513g}},
  doi          = {{10.1021/ol050513g}},
  volume       = {{7}},
  year         = {{2005}},
}