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Unusual C-H bond activation-aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster

Tunik, SP ; Balova, IA ; Borovitov, ME ; Nordlander, Ebbe LU ; Haukka, M and Pakkanen, TA (2002) In Journal of the Chemical Society. Dalton Transactions p.827-828
Abstract
Reactions of the triosmium cluster [HOs3(CO)(10)(eta(1):eta(1)-OC4H2CCH3)] with a series of aromatic aldehydes under mild conditions result in condensation of the ligand methyl group with the aldehyde C=O moiety to give typical aldol condensation products.
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author
; ; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
in
Journal of the Chemical Society. Dalton Transactions
issue
6
pages
827 - 828
publisher
Royal Society of Chemistry
external identifiers
  • wos:000174433000004
  • scopus:0036006311
ISSN
1472-7773
DOI
10.1039/b200707j
language
English
LU publication?
yes
additional info
The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
id
98107a9e-a164-41c0-9a6e-6c5f10b670af (old id 342002)
date added to LUP
2016-04-01 16:23:57
date last changed
2025-10-14 11:08:03
@article{98107a9e-a164-41c0-9a6e-6c5f10b670af,
  abstract     = {{Reactions of the triosmium cluster [HOs3(CO)(10)(eta(1):eta(1)-OC4H2CCH3)] with a series of aromatic aldehydes under mild conditions result in condensation of the ligand methyl group with the aldehyde C=O moiety to give typical aldol condensation products.}},
  author       = {{Tunik, SP and Balova, IA and Borovitov, ME and Nordlander, Ebbe and Haukka, M and Pakkanen, TA}},
  issn         = {{1472-7773}},
  language     = {{eng}},
  number       = {{6}},
  pages        = {{827--828}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Journal of the Chemical Society. Dalton Transactions}},
  title        = {{Unusual C-H bond activation-aldol condensation of aromatic aldehydes with the methyl group of a carbene-like triosmium cluster}},
  url          = {{http://dx.doi.org/10.1039/b200707j}},
  doi          = {{10.1039/b200707j}},
  year         = {{2002}},
}