Exploiting anisotropic particle shape to electrostatically assemble colloidal molecules with high yield and purity
Shelke, Yogesh ; Marín-Aguilar, Susana ; Camerin, Fabrizio LU
; Dijkstra, Marjolein
and Kraft, Daniela J.
(2023)
In Journal of Colloid and Interface Science
629.
p.322-333
- Abstract
Hypothesis: Colloidal molecules with anisotropic shapes and interactions are powerful model systems for deciphering the behavior of real molecules and building units for creating materials with designed properties. While many strategies for their assembly have been developed, they typically yield a broad distribution or are limited to a specific type. We hypothesize that the shape and relative sizes of colloidal particles can be exploited to efficiently direct their assembly into colloidal molecules of desired valence. Experiments: We exploit electrostatic self-assembly of negatively charged spheres made from either polystyrene or silica onto positively charged hematite cubes. We thoroughly analyze the role of the shape and size ratio... (More)
Hypothesis: Colloidal molecules with anisotropic shapes and interactions are powerful model systems for deciphering the behavior of real molecules and building units for creating materials with designed properties. While many strategies for their assembly have been developed, they typically yield a broad distribution or are limited to a specific type. We hypothesize that the shape and relative sizes of colloidal particles can be exploited to efficiently direct their assembly into colloidal molecules of desired valence. Experiments: We exploit electrostatic self-assembly of negatively charged spheres made from either polystyrene or silica onto positively charged hematite cubes. We thoroughly analyze the role of the shape and size ratio of particles on the cluster size and yield of colloidal molecules. Findings: Using a combination of experiments and simulations, we demonstrate that cubic particle shape is crucial to generate high yields of distinct colloidal molecules over a wide variety of size ratios. We find that electrostatic repulsion between the satellite spheres is important to leverage the templating effect of the cubes, leading the spheres to preferentially assemble on the facets rather than the edges and corners of the cube. The sixfold symmetry of cubes favors the assembly of molecules with six, four, and two satellite spheres at appropriate size ratios and interaction strength. Furthermore, we reveal that our protocol is not affected by the specific choice of the material of the colloidal particles. Finally, we show that the permanent magnetic dipole moment of the hematite cubes can be utilized to separate colloidal molecules from non-assembled satellite particles. Our simple and effective strategy might be extended to other templating particle shapes, thereby greatly expanding the library of colloidal molecules that can be achieved with high yield and purity.
(Less)
- author
- Shelke, Yogesh
; Marín-Aguilar, Susana
; Camerin, Fabrizio
LU
; Dijkstra, Marjolein
and Kraft, Daniela J.
- publishing date
- 2023-01
- type
- Contribution to journal
- publication status
- published
- keywords
- Anisotropic shape, Colloidal clusters, Monte Carlo simulations, Parking algorithm, Templated self-assembly
- in
- Journal of Colloid and Interface Science
- volume
- 629
- pages
- 12 pages
- publisher
- Elsevier
- external identifiers
-
- pmid:36081211
- scopus:85137170659
- ISSN
- 0021-9797
- DOI
- 10.1016/j.jcis.2022.08.158
- language
- English
- LU publication?
- no
- additional info
- Publisher Copyright: © 2022 The Authors
- id
- 9887fc09-2b5e-4dea-9011-2dbf732999c4
- date added to LUP
- 2024-02-22 14:06:36
- date last changed
- 2024-06-17 04:59:10
@article{9887fc09-2b5e-4dea-9011-2dbf732999c4,
abstract = {{<p>Hypothesis: Colloidal molecules with anisotropic shapes and interactions are powerful model systems for deciphering the behavior of real molecules and building units for creating materials with designed properties. While many strategies for their assembly have been developed, they typically yield a broad distribution or are limited to a specific type. We hypothesize that the shape and relative sizes of colloidal particles can be exploited to efficiently direct their assembly into colloidal molecules of desired valence. Experiments: We exploit electrostatic self-assembly of negatively charged spheres made from either polystyrene or silica onto positively charged hematite cubes. We thoroughly analyze the role of the shape and size ratio of particles on the cluster size and yield of colloidal molecules. Findings: Using a combination of experiments and simulations, we demonstrate that cubic particle shape is crucial to generate high yields of distinct colloidal molecules over a wide variety of size ratios. We find that electrostatic repulsion between the satellite spheres is important to leverage the templating effect of the cubes, leading the spheres to preferentially assemble on the facets rather than the edges and corners of the cube. The sixfold symmetry of cubes favors the assembly of molecules with six, four, and two satellite spheres at appropriate size ratios and interaction strength. Furthermore, we reveal that our protocol is not affected by the specific choice of the material of the colloidal particles. Finally, we show that the permanent magnetic dipole moment of the hematite cubes can be utilized to separate colloidal molecules from non-assembled satellite particles. Our simple and effective strategy might be extended to other templating particle shapes, thereby greatly expanding the library of colloidal molecules that can be achieved with high yield and purity.</p>}},
author = {{Shelke, Yogesh and Marín-Aguilar, Susana and Camerin, Fabrizio and Dijkstra, Marjolein and Kraft, Daniela J.}},
issn = {{0021-9797}},
keywords = {{Anisotropic shape; Colloidal clusters; Monte Carlo simulations; Parking algorithm; Templated self-assembly}},
language = {{eng}},
pages = {{322--333}},
publisher = {{Elsevier}},
series = {{Journal of Colloid and Interface Science}},
title = {{Exploiting anisotropic particle shape to electrostatically assemble colloidal molecules with high yield and purity}},
url = {{http://dx.doi.org/10.1016/j.jcis.2022.08.158}},
doi = {{10.1016/j.jcis.2022.08.158}},
volume = {{629}},
year = {{2023}},
}