trans-Influence of Triphenyl Stibine. Crystal and Molecular Structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]
(1998) In Inorganica Chimica Acta 1998(277). p.237-241- Abstract
- Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.
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- author
- Wendt, Ola LU ; Scodinu, Allessandra and Elding, Lars Ivar LU
- organization
- publishing date
- 1998-09-21
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- trans-influence, crystal structure, stibine complex, palladium(ii), Platinum(II) complexes, Stibine complexes, Crystal structure, trans-influence, IR and Raman data
- in
- Inorganica Chimica Acta
- volume
- 1998
- issue
- 277
- pages
- 5 pages
- publisher
- Elsevier
- external identifiers
-
- scopus:0001763941
- ISSN
- 0020-1693
- DOI
- 10.1016/S0020-1693(97)06130-6
- language
- English
- LU publication?
- yes
- id
- 9cdf74c4-c1ce-441f-bd60-e04d88c04051
- date added to LUP
- 2016-12-27 21:01:52
- date last changed
- 2022-01-30 08:48:44
@article{9cdf74c4-c1ce-441f-bd60-e04d88c04051, abstract = {{Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.}}, author = {{Wendt, Ola and Scodinu, Allessandra and Elding, Lars Ivar}}, issn = {{0020-1693}}, keywords = {{trans-influence; crystal structure; stibine complex; palladium(ii); Platinum(II) complexes; Stibine complexes; Crystal structure; trans-influence; IR and Raman data}}, language = {{eng}}, month = {{09}}, number = {{277}}, pages = {{237--241}}, publisher = {{Elsevier}}, series = {{Inorganica Chimica Acta}}, title = {{trans-Influence of Triphenyl Stibine. Crystal and Molecular Structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]}}, url = {{http://dx.doi.org/10.1016/S0020-1693(97)06130-6}}, doi = {{10.1016/S0020-1693(97)06130-6}}, volume = {{1998}}, year = {{1998}}, }