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trans-Influence of Triphenyl Stibine. Crystal and Molecular Structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]

Wendt, Ola LU ; Scodinu, Allessandra and Elding, Lars Ivar LU (1998) In Inorganica Chimica Acta 1998(277). p.237-241
Abstract
Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.
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organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
trans-influence, crystal structure, stibine complex, palladium(ii), Platinum(II) complexes, Stibine complexes, Crystal structure, trans-influence, IR and Raman data
in
Inorganica Chimica Acta
volume
1998
issue
277
pages
5 pages
publisher
Elsevier
external identifiers
  • scopus:0001763941
ISSN
0020-1693
DOI
10.1016/S0020-1693(97)06130-6
language
English
LU publication?
yes
id
9cdf74c4-c1ce-441f-bd60-e04d88c04051
date added to LUP
2016-12-27 21:01:52
date last changed
2022-01-30 08:48:44
@article{9cdf74c4-c1ce-441f-bd60-e04d88c04051,
  abstract     = {{Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.}},
  author       = {{Wendt, Ola and Scodinu, Allessandra and Elding, Lars Ivar}},
  issn         = {{0020-1693}},
  keywords     = {{trans-influence; crystal structure; stibine complex; palladium(ii); Platinum(II)  complexes; Stibine complexes; Crystal structure; trans-influence; IR and Raman data}},
  language     = {{eng}},
  month        = {{09}},
  number       = {{277}},
  pages        = {{237--241}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{trans-Influence of Triphenyl Stibine. Crystal and Molecular Structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]}},
  url          = {{http://dx.doi.org/10.1016/S0020-1693(97)06130-6}},
  doi          = {{10.1016/S0020-1693(97)06130-6}},
  volume       = {{1998}},
  year         = {{1998}},
}