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trans-Influence of Triphenyl Stibine. Crystal and Molecular Structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]

Wendt, Ola LU ; Scodinu, Allessandra and Elding, Lars Ivar LU (1998) In Inorganica Chimica Acta 1998(277). p.237-241
Abstract
Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed.
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author
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
trans-influence, crystal structure, stibine complex, palladium(ii), Platinum(II) complexes, Stibine complexes, Crystal structure, trans-influence, IR and Raman data
in
Inorganica Chimica Acta
volume
1998
issue
277
pages
5 pages
publisher
Elsevier
external identifiers
  • scopus:0001763941
ISSN
0020-1693
DOI
10.1016/S0020-1693(97)06130-6
language
English
LU publication?
yes
id
9cdf74c4-c1ce-441f-bd60-e04d88c04051
date added to LUP
2016-12-27 21:01:52
date last changed
2017-03-20 21:32:31
@article{9cdf74c4-c1ce-441f-bd60-e04d88c04051,
  abstract     = {Crystals of cis-[PtCl2(SbPh3)(2)] (1) are monoclinic, space group P2(1)/a with a = 20.5708(12), b = 10.1942(4), c = 33.3984(15) Angstrom, beta = 94.394(4)degrees and Z = 8. Substitution of chloride for iodide yields trans-[PtI2(SbPh3)(2)] (2), the crystals of which are monoclinic, space group P2(1)/c with a = 18.108(4), b = 10.102(2), c = 19.1 15(5) Angstrom, beta = 95.241(16)degrees and Z = 4. The average Pt-Cl distance in 1 is 2.338(12) Angstrom, implying a trans influence of triphenyl stibine comparable with that of triphenyl phosphine, as opposed to what has been reported earlier. IR and Raman data for 1 and 2 are reported and discussed. },
  author       = {Wendt, Ola and Scodinu, Allessandra and Elding, Lars Ivar},
  issn         = {0020-1693},
  keyword      = {trans-influence,crystal structure,stibine complex,palladium(ii),Platinum(II)  complexes,Stibine complexes,Crystal structure,trans-influence,IR and Raman data},
  language     = {eng},
  month        = {09},
  number       = {277},
  pages        = {237--241},
  publisher    = {Elsevier},
  series       = {Inorganica Chimica Acta},
  title        = {trans-Influence of Triphenyl Stibine. Crystal and Molecular Structures of cis-[PtCl2(SbPh3)2] and trans-[PtI2(SbPh3)2]},
  url          = {http://dx.doi.org/10.1016/S0020-1693(97)06130-6},
  volume       = {1998},
  year         = {1998},
}