Skip to main content

Lund University Publications

LUND UNIVERSITY LIBRARIES

A demonstration of an affinity between pyrite and organic matter in a hydrothermal setting

Lindgren, Paula LU ; Parnell, John ; Holm, Nils G. and Broman, Curt (2011) In Geochemical Transactions 12.
Abstract

One of the key-principles of the iron-sulphur world theory is to bring organic molecules close enough to interact with each other, using the surface of pyrite as a substrate in a hydrothermal setting. The present paper explores the relationship of pyrite and organic matter in a hydrothermal setting from the geological record; in hydrothermal calcite veins from Carboniferous limestones in central Ireland. Here, the organic matter is accumulated as coatings around, and through, pyrite grains. Most of the pyrite grains are euhedral-subhedral crystals, ranging in size from ca 0.1-0.5 mm in diameter, and they are scattered throughout the matrix of the vein calcite. The organic matter was deposited from a hydrothermal fluid at a temperature... (More)

One of the key-principles of the iron-sulphur world theory is to bring organic molecules close enough to interact with each other, using the surface of pyrite as a substrate in a hydrothermal setting. The present paper explores the relationship of pyrite and organic matter in a hydrothermal setting from the geological record; in hydrothermal calcite veins from Carboniferous limestones in central Ireland. Here, the organic matter is accumulated as coatings around, and through, pyrite grains. Most of the pyrite grains are euhedral-subhedral crystals, ranging in size from ca 0.1-0.5 mm in diameter, and they are scattered throughout the matrix of the vein calcite. The organic matter was deposited from a hydrothermal fluid at a temperature of at least 200C, and gives a Raman signature of disordered carbon. This study points to an example from a hydrothermal setting in the geological record, demonstrating that pyrite can have a high potential for the concentration and accumulation of organic materials.

(Less)
Please use this url to cite or link to this publication:
author
; ; and
publishing date
type
Contribution to journal
publication status
published
subject
in
Geochemical Transactions
volume
12
article number
3
publisher
BioMed Central (BMC)
external identifiers
  • scopus:79551621468
DOI
10.1186/1467-4866-12-3
language
English
LU publication?
no
id
9d615441-5eae-4101-bea6-7b59ba1c0624
date added to LUP
2017-06-26 09:51:08
date last changed
2022-03-16 23:18:53
@article{9d615441-5eae-4101-bea6-7b59ba1c0624,
  abstract     = {{<p>One of the key-principles of the iron-sulphur world theory is to bring organic molecules close enough to interact with each other, using the surface of pyrite as a substrate in a hydrothermal setting. The present paper explores the relationship of pyrite and organic matter in a hydrothermal setting from the geological record; in hydrothermal calcite veins from Carboniferous limestones in central Ireland. Here, the organic matter is accumulated as coatings around, and through, pyrite grains. Most of the pyrite grains are euhedral-subhedral crystals, ranging in size from ca 0.1-0.5 mm in diameter, and they are scattered throughout the matrix of the vein calcite. The organic matter was deposited from a hydrothermal fluid at a temperature of at least 200C, and gives a Raman signature of disordered carbon. This study points to an example from a hydrothermal setting in the geological record, demonstrating that pyrite can have a high potential for the concentration and accumulation of organic materials.</p>}},
  author       = {{Lindgren, Paula and Parnell, John and Holm, Nils G. and Broman, Curt}},
  language     = {{eng}},
  month        = {{02}},
  publisher    = {{BioMed Central (BMC)}},
  series       = {{Geochemical Transactions}},
  title        = {{A demonstration of an affinity between pyrite and organic matter in a hydrothermal setting}},
  url          = {{http://dx.doi.org/10.1186/1467-4866-12-3}},
  doi          = {{10.1186/1467-4866-12-3}},
  volume       = {{12}},
  year         = {{2011}},
}