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Mesoporous titanium dioxide films using partially fluorinated surfactant templates in ethanol

Hawley, Adrian M. ; Edler, Karen J. LU orcid and Roser, Stephen J. (2011) In Journal of Materials Chemistry 21(36). p.14062-14071
Abstract

Mesoporous titanium dioxide films have been produced via a self assembly pathway at the air-ethanol interface using partially fluorinated surfactants as structure directing agents. The high level of surface activity displayed by partially fluorinated compounds in alcohols has been used to generate an ordered film at the air-solution interface, as titanium oligomers condense into an ordered inorganic network. The minimisation and exclusion of water in these preparations directs structure formation at the interface and slows the titania polymerisation. X-ray scattering and Brewster angle microscopy techniques have been used to study the formation and structure of these materials.

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author
; and
publishing date
type
Contribution to journal
publication status
published
in
Journal of Materials Chemistry
volume
21
issue
36
pages
10 pages
publisher
Royal Society of Chemistry
external identifiers
  • scopus:80052325908
ISSN
0959-9428
DOI
10.1039/c1jm10963d
language
English
LU publication?
no
id
9deabfe3-1f3e-42ae-b461-fb204adc8dc0
date added to LUP
2023-05-04 18:25:44
date last changed
2023-06-09 14:15:06
@article{9deabfe3-1f3e-42ae-b461-fb204adc8dc0,
  abstract     = {{<p>Mesoporous titanium dioxide films have been produced via a self assembly pathway at the air-ethanol interface using partially fluorinated surfactants as structure directing agents. The high level of surface activity displayed by partially fluorinated compounds in alcohols has been used to generate an ordered film at the air-solution interface, as titanium oligomers condense into an ordered inorganic network. The minimisation and exclusion of water in these preparations directs structure formation at the interface and slows the titania polymerisation. X-ray scattering and Brewster angle microscopy techniques have been used to study the formation and structure of these materials.</p>}},
  author       = {{Hawley, Adrian M. and Edler, Karen J. and Roser, Stephen J.}},
  issn         = {{0959-9428}},
  language     = {{eng}},
  month        = {{09}},
  number       = {{36}},
  pages        = {{14062--14071}},
  publisher    = {{Royal Society of Chemistry}},
  series       = {{Journal of Materials Chemistry}},
  title        = {{Mesoporous titanium dioxide films using partially fluorinated surfactant templates in ethanol}},
  url          = {{http://dx.doi.org/10.1039/c1jm10963d}},
  doi          = {{10.1039/c1jm10963d}},
  volume       = {{21}},
  year         = {{2011}},
}