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Synthesis of New Thiol Derivatives of Os3(CO)12; Crystal Structure of HOs3(CO)10(SBut)

Monari, Magda ; Pfeiffer, Ragen ; Rudsander, Ulla and Nordlander, Ebbe LU (1996) In Inorganica Chimica Acta 247(1). p.131-134
Abstract
The clusters [Os3(CO) 10(/z-H) {/z-SC(CH3)3} ] (1) and [Os3(CO) to(/z-H) {p-SCeHH } ] (2) have been synthesized by addition of the

appropriate thiol RSH (R ffi C(CH3)3, CeHH) to [Os3(CO) it (NCMe) ] or [Os3(CO) io(NCMe)2] in dichloromethane. Clusters 1 and 2

have been characterized by 1R, NMR, mass speetromet~, and, in the case of 1, X-ray crystallography. Compound I crystallizes in space group

P2~/n (affi9.507(1), bffi 12.860(1), cffi 17.838(3) A, flffi99.77(1) °, Zffi4). The molecule conforms to an idealized C, symmetry. The

bond distances in the osmium triangle average 2.860 A; there is no significant elongation of the Os-Os edge in I that is bridged by the hydride

and the thiolate moiety.
Please use this url to cite or link to this publication:
author
; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
Cluster complexes, Crystal structures, Thiolate complexes, Osmium complexes, Carbonyl complexes, Hydride complexes
in
Inorganica Chimica Acta
volume
247
issue
1
pages
131 - 134
publisher
Elsevier
external identifiers
  • scopus:0000903527
ISSN
0020-1693
DOI
10.1016/0020-1693(95)04832-4
language
English
LU publication?
yes
id
a4927d3d-43b4-4b33-af44-9c39bb785580 (old id 961004)
date added to LUP
2016-04-01 17:06:26
date last changed
2022-01-29 00:23:03
@article{a4927d3d-43b4-4b33-af44-9c39bb785580,
  abstract     = {{The clusters [Os3(CO) 10(/z-H) {/z-SC(CH3)3} ] (1) and [Os3(CO) to(/z-H) {p-SCeHH } ] (2) have been synthesized by addition of the<br/><br>
appropriate thiol RSH (R ffi C(CH3)3, CeHH) to [Os3(CO) it (NCMe) ] or [Os3(CO) io(NCMe)2] in dichloromethane. Clusters 1 and 2<br/><br>
have been characterized by 1R, NMR, mass speetromet~, and, in the case of 1, X-ray crystallography. Compound I crystallizes in space group<br/><br>
P2~/n (affi9.507(1), bffi 12.860(1), cffi 17.838(3) A, flffi99.77(1) °, Zffi4). The molecule conforms to an idealized C, symmetry. The<br/><br>
bond distances in the osmium triangle average 2.860 A; there is no significant elongation of the Os-Os edge in I that is bridged by the hydride<br/><br>
and the thiolate moiety.}},
  author       = {{Monari, Magda and Pfeiffer, Ragen and Rudsander, Ulla and Nordlander, Ebbe}},
  issn         = {{0020-1693}},
  keywords     = {{Cluster complexes; Crystal structures; Thiolate complexes; Osmium complexes; Carbonyl complexes; Hydride complexes}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{131--134}},
  publisher    = {{Elsevier}},
  series       = {{Inorganica Chimica Acta}},
  title        = {{Synthesis of New Thiol Derivatives of Os3(CO)12; Crystal Structure of HOs3(CO)10(SBut)}},
  url          = {{http://dx.doi.org/10.1016/0020-1693(95)04832-4}},
  doi          = {{10.1016/0020-1693(95)04832-4}},
  volume       = {{247}},
  year         = {{1996}},
}