Reactivity of the triruthenium ortho-metalated cluster [Ru-3(CO)(9){mu(3)- eta(1), kappa(1),kappa(2)-PhP( C6H4) CH2PPh}] with tri(2-thienyl) phosphine and tri( 2-furyl) phosphine: Formation of 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine complexes via phosphorus-carbon bond formation
(2009) In Journal of Organometallic Chemistry 694(20). p.3312-3319- Abstract
- Reaction of [Ru(CO)(9){mu(3-)eta(1),kappa(1),kappa(2)-PhP(C6H4)CH2PPh}] (1) with tri(2-thienyl) phosphine (PTh3) in refluxing THF afforded [Ru-3(CO)(9)(PTh3)(mu-dpbm)] (3){dpbm = PhP(C6H4)(CH2)PPh} and [Ru-3(CO)(6)(mu-CO)(2){mu-kappa(1),eta(1)-PTh2(C4H2S)}{mu(3)-kappa(1),ka ppa(2)-Ph2PCH2PPh}] (5) in 18% and 12% yields, respectively, while a similar reaction with tri(2-furyl)phosphine (PFu(3)) gave [Ru-3(CO)(9)(PFu(3))(mu-dpbm)] (4) and [Ru-3(CO)(7)(mu-eta(1),eta(2)-C4H3O)(mu-PFu(2)){mu(3)-eta(1),kappa(1),ka ppa(2)-PhP(C6H4)CH2PPh}] (6) in 24% and 27% yields, respectively. Compounds 2 and 4 are phosphine adducts of 1 in which the diphosphine ligand is transformed into 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine(dpbm) via... (More)
- Reaction of [Ru(CO)(9){mu(3-)eta(1),kappa(1),kappa(2)-PhP(C6H4)CH2PPh}] (1) with tri(2-thienyl) phosphine (PTh3) in refluxing THF afforded [Ru-3(CO)(9)(PTh3)(mu-dpbm)] (3){dpbm = PhP(C6H4)(CH2)PPh} and [Ru-3(CO)(6)(mu-CO)(2){mu-kappa(1),eta(1)-PTh2(C4H2S)}{mu(3)-kappa(1),ka ppa(2)-Ph2PCH2PPh}] (5) in 18% and 12% yields, respectively, while a similar reaction with tri(2-furyl)phosphine (PFu(3)) gave [Ru-3(CO)(9)(PFu(3))(mu-dpbm)] (4) and [Ru-3(CO)(7)(mu-eta(1),eta(2)-C4H3O)(mu-PFu(2)){mu(3)-eta(1),kappa(1),ka ppa(2)-PhP(C6H4)CH2PPh}] (6) in 24% and 27% yields, respectively. Compounds 2 and 4 are phosphine adducts of 1 in which the diphosphine ligand is transformed into 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine(dpbm) via phosphorus-carbon bond formation. Cluster 5 results from metalation of a thienyl ring, the cleved proton being transfoerred to the diphosphine.Carbon-phosphorus bond clevarge of a PFu(3) ligand is observed in 6 to afford a phosphido-bridge and furyl fragment, the latter bridging in a sigma,pi-vinyl fashion. The molecular strucutres of 3,5 and 6 have been determined by X-ray diffraction studies. (C) 2009 Published by Elsevier B.V. (Less)
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https://lup.lub.lu.se/record/1477242
- author
- Ghosh, Shishir ; Rana, Shahed ; Tocher, Derek A. ; Hogarth, Graeme ; Nordlander, Ebbe LU and Kabir, Shariff E.
- organization
- publishing date
- 2009
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- X-ray structures, Tri(2-furyl) phosphine, Tri(2-thienyl) phosphine, Carbonyl, Diphosphines, Triruthenium
- in
- Journal of Organometallic Chemistry
- volume
- 694
- issue
- 20
- pages
- 3312 - 3319
- publisher
- Elsevier
- external identifiers
-
- wos:000268988500014
- scopus:68549120870
- ISSN
- 0022-328X
- DOI
- 10.1016/j.jorganchem.2009.06.005
- language
- English
- LU publication?
- yes
- additional info
- The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)
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- a7a78811-e473-454f-9068-799d1603b868 (old id 1477242)
- date added to LUP
- 2016-04-01 14:16:33
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- 2022-02-19 18:01:20
@article{a7a78811-e473-454f-9068-799d1603b868,
abstract = {{Reaction of [Ru(CO)(9){mu(3-)eta(1),kappa(1),kappa(2)-PhP(C6H4)CH2PPh}] (1) with tri(2-thienyl) phosphine (PTh3) in refluxing THF afforded [Ru-3(CO)(9)(PTh3)(mu-dpbm)] (3){dpbm = PhP(C6H4)(CH2)PPh} and [Ru-3(CO)(6)(mu-CO)(2){mu-kappa(1),eta(1)-PTh2(C4H2S)}{mu(3)-kappa(1),ka ppa(2)-Ph2PCH2PPh}] (5) in 18% and 12% yields, respectively, while a similar reaction with tri(2-furyl)phosphine (PFu(3)) gave [Ru-3(CO)(9)(PFu(3))(mu-dpbm)] (4) and [Ru-3(CO)(7)(mu-eta(1),eta(2)-C4H3O)(mu-PFu(2)){mu(3)-eta(1),kappa(1),ka ppa(2)-PhP(C6H4)CH2PPh}] (6) in 24% and 27% yields, respectively. Compounds 2 and 4 are phosphine adducts of 1 in which the diphosphine ligand is transformed into 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine(dpbm) via phosphorus-carbon bond formation. Cluster 5 results from metalation of a thienyl ring, the cleved proton being transfoerred to the diphosphine.Carbon-phosphorus bond clevarge of a PFu(3) ligand is observed in 6 to afford a phosphido-bridge and furyl fragment, the latter bridging in a sigma,pi-vinyl fashion. The molecular strucutres of 3,5 and 6 have been determined by X-ray diffraction studies. (C) 2009 Published by Elsevier B.V.}},
author = {{Ghosh, Shishir and Rana, Shahed and Tocher, Derek A. and Hogarth, Graeme and Nordlander, Ebbe and Kabir, Shariff E.}},
issn = {{0022-328X}},
keywords = {{X-ray structures; Tri(2-furyl) phosphine; Tri(2-thienyl) phosphine; Carbonyl; Diphosphines; Triruthenium}},
language = {{eng}},
number = {{20}},
pages = {{3312--3319}},
publisher = {{Elsevier}},
series = {{Journal of Organometallic Chemistry}},
title = {{Reactivity of the triruthenium ortho-metalated cluster [Ru-3(CO)(9){mu(3)- eta(1), kappa(1),kappa(2)-PhP( C6H4) CH2PPh}] with tri(2-thienyl) phosphine and tri( 2-furyl) phosphine: Formation of 1,3-diphenyl-2,3-dihydro-1H-1,3-benzodiphosphine complexes via phosphorus-carbon bond formation}},
url = {{http://dx.doi.org/10.1016/j.jorganchem.2009.06.005}},
doi = {{10.1016/j.jorganchem.2009.06.005}},
volume = {{694}},
year = {{2009}},
}