Dissociation of As-4 clusters following valence photoionization and 3d core excitation
(2012) In Physical Review A (Atomic, Molecular and Optical Physics) 86(2).- Abstract
- The VUV-induced photofragmentation of As-4 clusters was studied using photoelectron-photoion-coincidence (PEPICO) spectroscopy. The fragmentation pathways subsequent to outer and inner valence photoionization and resonant photoexcitation were studied by examining the cationic production as a function of electron energy. In addition, regular photoelectron spectroscopy and partial ion yield absorption spectroscopy were employed. In order to enhance the weak signal from the inner valence states, resonant core 3d excitation was used in the PEPICO experiment. The fragmentation pathways were inspected with the aid of ab initio and thermochemical calculations. The many-electron effects were found to play a major role in the observed inner valence... (More)
- The VUV-induced photofragmentation of As-4 clusters was studied using photoelectron-photoion-coincidence (PEPICO) spectroscopy. The fragmentation pathways subsequent to outer and inner valence photoionization and resonant photoexcitation were studied by examining the cationic production as a function of electron energy. In addition, regular photoelectron spectroscopy and partial ion yield absorption spectroscopy were employed. In order to enhance the weak signal from the inner valence states, resonant core 3d excitation was used in the PEPICO experiment. The fragmentation pathways were inspected with the aid of ab initio and thermochemical calculations. The many-electron effects were found to play a major role in the observed inner valence structure and resulting photofragmentation. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3073584
- author
- Kettunen, J. A. ; Urpelainen, Samuli LU ; Heinasmaki, S. and Huttula, M.
- organization
- publishing date
- 2012
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Review A (Atomic, Molecular and Optical Physics)
- volume
- 86
- issue
- 2
- article number
- 023201
- publisher
- American Physical Society
- external identifiers
-
- wos:000307125600005
- scopus:84864656028
- ISSN
- 1050-2947
- DOI
- 10.1103/PhysRevA.86.023201
- language
- English
- LU publication?
- yes
- id
- a982fb18-caf6-4f69-ba15-bb1eb98fdb8d (old id 3073584)
- date added to LUP
- 2016-04-01 10:46:16
- date last changed
- 2022-01-26 02:21:15
@article{a982fb18-caf6-4f69-ba15-bb1eb98fdb8d,
abstract = {{The VUV-induced photofragmentation of As-4 clusters was studied using photoelectron-photoion-coincidence (PEPICO) spectroscopy. The fragmentation pathways subsequent to outer and inner valence photoionization and resonant photoexcitation were studied by examining the cationic production as a function of electron energy. In addition, regular photoelectron spectroscopy and partial ion yield absorption spectroscopy were employed. In order to enhance the weak signal from the inner valence states, resonant core 3d excitation was used in the PEPICO experiment. The fragmentation pathways were inspected with the aid of ab initio and thermochemical calculations. The many-electron effects were found to play a major role in the observed inner valence structure and resulting photofragmentation.}},
author = {{Kettunen, J. A. and Urpelainen, Samuli and Heinasmaki, S. and Huttula, M.}},
issn = {{1050-2947}},
language = {{eng}},
number = {{2}},
publisher = {{American Physical Society}},
series = {{Physical Review A (Atomic, Molecular and Optical Physics)}},
title = {{Dissociation of As-4 clusters following valence photoionization and 3d core excitation}},
url = {{http://dx.doi.org/10.1103/PhysRevA.86.023201}},
doi = {{10.1103/PhysRevA.86.023201}},
volume = {{86}},
year = {{2012}},
}