A detailed chemical reaction mechanism for the oxidation of hydrocarbons and its application to the analysis of benzene formation in fuel-rich premixed laminar acetylene and propene flames
(2004) In Physical Chemistry Chemical Physics 6(14). p.3824-3835- Abstract
- On the basis of existing detailed kinetic schemes a general and consistent mechanism of the oxidation of hydrocarbons and the formation of higher hydrocarbons was compiled for computational studies covering the characteristic properties of a wide range of combustion processes. Computed ignition delay times of hydrocarbon -oxygen mixtures (CH4-, C2H6-, C3H8-, n-C4H10-, CH4 + C2H6-, C2H4, C3H6-O-2) match the experimental values. The calculated absolute flame velocities of laminar premixed flames (CH4-, C2H6-, C3H8-, n-C4H10-, C2H4-, C3H6-, and C2H2-air) and the dependence on mixture strength agree with the latest experimental investigations reported in the literature. With the same model concentration profiles for major and intermediate... (More)
- On the basis of existing detailed kinetic schemes a general and consistent mechanism of the oxidation of hydrocarbons and the formation of higher hydrocarbons was compiled for computational studies covering the characteristic properties of a wide range of combustion processes. Computed ignition delay times of hydrocarbon -oxygen mixtures (CH4-, C2H6-, C3H8-, n-C4H10-, CH4 + C2H6-, C2H4, C3H6-O-2) match the experimental values. The calculated absolute flame velocities of laminar premixed flames (CH4-, C2H6-, C3H8-, n-C4H10-, C2H4-, C3H6-, and C2H2-air) and the dependence on mixture strength agree with the latest experimental investigations reported in the literature. With the same model concentration profiles for major and intermediate species in fuel-rich, non-sooting, premixed C2H2-, C3H6- air flames and a mixed C2H2/C3H6 (1:1)-air flame at 50 mbar are predicted in good agreement with experimental data. An analysis of reaction pathways shows for all three flames that benzene formation can be described by propargyl combination. (Less)
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/269141
- author
- Hoyermann, K ; Mauss, Fabian LU and Zeuch, T
- organization
- publishing date
- 2004
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Physical Chemistry Chemical Physics
- volume
- 6
- issue
- 14
- pages
- 3824 - 3835
- publisher
- Royal Society of Chemistry
- external identifiers
-
- wos:000223472600006
- scopus:4344577241
- ISSN
- 1463-9084
- DOI
- 10.1039/b404632c
- language
- English
- LU publication?
- yes
- id
- acd12831-7407-40c7-94b7-2a26929e4e66 (old id 269141)
- date added to LUP
- 2016-04-01 16:29:20
- date last changed
- 2022-03-15 00:50:44
@article{acd12831-7407-40c7-94b7-2a26929e4e66, abstract = {{On the basis of existing detailed kinetic schemes a general and consistent mechanism of the oxidation of hydrocarbons and the formation of higher hydrocarbons was compiled for computational studies covering the characteristic properties of a wide range of combustion processes. Computed ignition delay times of hydrocarbon -oxygen mixtures (CH4-, C2H6-, C3H8-, n-C4H10-, CH4 + C2H6-, C2H4, C3H6-O-2) match the experimental values. The calculated absolute flame velocities of laminar premixed flames (CH4-, C2H6-, C3H8-, n-C4H10-, C2H4-, C3H6-, and C2H2-air) and the dependence on mixture strength agree with the latest experimental investigations reported in the literature. With the same model concentration profiles for major and intermediate species in fuel-rich, non-sooting, premixed C2H2-, C3H6- air flames and a mixed C2H2/C3H6 (1:1)-air flame at 50 mbar are predicted in good agreement with experimental data. An analysis of reaction pathways shows for all three flames that benzene formation can be described by propargyl combination.}}, author = {{Hoyermann, K and Mauss, Fabian and Zeuch, T}}, issn = {{1463-9084}}, language = {{eng}}, number = {{14}}, pages = {{3824--3835}}, publisher = {{Royal Society of Chemistry}}, series = {{Physical Chemistry Chemical Physics}}, title = {{A detailed chemical reaction mechanism for the oxidation of hydrocarbons and its application to the analysis of benzene formation in fuel-rich premixed laminar acetylene and propene flames}}, url = {{http://dx.doi.org/10.1039/b404632c}}, doi = {{10.1039/b404632c}}, volume = {{6}}, year = {{2004}}, }