Catalysis as a resonance effect, V. Factors that determine the isokinetic temperature in catalytic reactions
(1999) In Reaction Kinetics and Catalysis Letters 68(1). p.115-124- Abstract
- When describing isokinetic effects by the model of selective energy transfer by resonance, it is sometimes found that the frequency of the forcing oscillator is quite different to that of the reacting molecule, i.e."resonance" is not a very good concept to use. By noting that the two frequencies thus found are related to each other as the ratios of small integers, e.g. 4:3, this dilemma is resolved. The investigation covers formic acid decomposition, homogeneous ligand displacement reactions of Ni(DMSO)(6)(2+) and the dissociation of CO2 on metal surfaces.
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/3917623
- author
- Larsson, Ragnar LU
- organization
- publishing date
- 1999
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- resonance effect, isokinetic temperature, catalytic reactions
- in
- Reaction Kinetics and Catalysis Letters
- volume
- 68
- issue
- 1
- pages
- 115 - 124
- publisher
- Springer
- external identifiers
-
- wos:000082492200013
- scopus:0000519399
- ISSN
- 1588-2837
- DOI
- 10.1007/BF02475493
- language
- English
- LU publication?
- yes
- id
- acd6ef1e-41e0-4153-8634-bfb735796c18 (old id 3917623)
- date added to LUP
- 2016-04-01 12:08:00
- date last changed
- 2023-12-10 11:47:51
@article{acd6ef1e-41e0-4153-8634-bfb735796c18, abstract = {{When describing isokinetic effects by the model of selective energy transfer by resonance, it is sometimes found that the frequency of the forcing oscillator is quite different to that of the reacting molecule, i.e."resonance" is not a very good concept to use. By noting that the two frequencies thus found are related to each other as the ratios of small integers, e.g. 4:3, this dilemma is resolved. The investigation covers formic acid decomposition, homogeneous ligand displacement reactions of Ni(DMSO)(6)(2+) and the dissociation of CO2 on metal surfaces.}}, author = {{Larsson, Ragnar}}, issn = {{1588-2837}}, keywords = {{resonance effect; isokinetic temperature; catalytic reactions}}, language = {{eng}}, number = {{1}}, pages = {{115--124}}, publisher = {{Springer}}, series = {{Reaction Kinetics and Catalysis Letters}}, title = {{Catalysis as a resonance effect, V. Factors that determine the isokinetic temperature in catalytic reactions}}, url = {{http://dx.doi.org/10.1007/BF02475493}}, doi = {{10.1007/BF02475493}}, volume = {{68}}, year = {{1999}}, }