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Modelling of Mass and Heat Transport in Paper - Evaluation of Mechanisms and Shrinkage

Baggerud, Erik LU (2004)
Abstract
In this work a one-dimensional model for the mass and heat transport in the thickness direction of paper has been developed. Solid-based coordinates were applied to simplify incorporation of shrinkage. Liquid diffusion, gas convection and vapour and air diffusion were incorporated as mass transport mechansims. In the heat balance the convective heat transport and heat conduction were included. Specific models for the transport parameters were developed from data in the literature.



The model was evaluated for four cases of drying where moisture and temperature distribution data through the thickness of paper are available. An algorithm was proposed to calculate unknown parameters directly from the experimental data. Three... (More)
In this work a one-dimensional model for the mass and heat transport in the thickness direction of paper has been developed. Solid-based coordinates were applied to simplify incorporation of shrinkage. Liquid diffusion, gas convection and vapour and air diffusion were incorporated as mass transport mechansims. In the heat balance the convective heat transport and heat conduction were included. Specific models for the transport parameters were developed from data in the literature.



The model was evaluated for four cases of drying where moisture and temperature distribution data through the thickness of paper are available. An algorithm was proposed to calculate unknown parameters directly from the experimental data. Three remaining parameters were obtained by non-linear regression of calculated moisture and temperature distribution to the experimental data.



Simulations showed that the model can predict the drying behaviour and the moisture and temperature gradients for convective drying of kraft, and hot surface drying of kraft and sulphite pulp sheets with low density. For high-density sheets the general behaviour was correctly predicted, but moisutre and temperature gradients deviated more from the experimental data, than in the case of low-density sheets. The mechanisms governing the drying behaviour were investigated.



Shrinkage behaviour and volume fractions of solid, liquid and gas in kraft and CTMP sheets have been measured using the mercury displacement technique. The gas volume fraction increases continuously with decreasing moisture ratio. Influence of basis weight, pressing and beating was also investigated.



A triangular phase diagram was developed in which the phase development and shrinkage behaviour of paper can be studied. Analysis showed that kraft sheets shrink continuously in the moisture ranges investigated, while highly refined CTMP sheets showed a region with no shrinkage. Analysis and modelling of the shrinkage behaviour showed that the shrinkage is higher than ideal shrinkage for moisture ratios below approximately 1.0 kg water/kg DS. (Less)
Please use this url to cite or link to this publication:
author
supervisor
opponent
  • Prof. Ramaswamy, Shri, Department of Wood and Paper Science, University of Minnesota, Minneapolis, USA
organization
publishing date
type
Thesis
publication status
published
subject
keywords
solid-based coordinates, paper, porous medium, convection, diffusion, volume fractions, mercury displacement, shrinkage, simulations, convective, hot surface, Modelling, drying, Wood, pulp and paper technology, Pappers- och massateknik
pages
275 pages
publisher
Chemical Engineering, Lund University
defense location
Room K:C, Kemicentrum, Getingevägen 60, Lund Institute of Technology.
defense date
2004-02-06 13:15:00
external identifiers
  • other:ISRN: LUTKDH/TKKA-1001/1-228/(2004)
ISBN
91-7422-042-X
language
English
LU publication?
yes
id
b67e9ea0-ab0f-4356-a2cb-d57674f588e4 (old id 21539)
date added to LUP
2016-04-01 16:51:51
date last changed
2018-11-21 20:44:48
@phdthesis{b67e9ea0-ab0f-4356-a2cb-d57674f588e4,
  abstract     = {{In this work a one-dimensional model for the mass and heat transport in the thickness direction of paper has been developed. Solid-based coordinates were applied to simplify incorporation of shrinkage. Liquid diffusion, gas convection and vapour and air diffusion were incorporated as mass transport mechansims. In the heat balance the convective heat transport and heat conduction were included. Specific models for the transport parameters were developed from data in the literature.<br/><br>
<br/><br>
The model was evaluated for four cases of drying where moisture and temperature distribution data through the thickness of paper are available. An algorithm was proposed to calculate unknown parameters directly from the experimental data. Three remaining parameters were obtained by non-linear regression of calculated moisture and temperature distribution to the experimental data.<br/><br>
<br/><br>
Simulations showed that the model can predict the drying behaviour and the moisture and temperature gradients for convective drying of kraft, and hot surface drying of kraft and sulphite pulp sheets with low density. For high-density sheets the general behaviour was correctly predicted, but moisutre and temperature gradients deviated more from the experimental data, than in the case of low-density sheets. The mechanisms governing the drying behaviour were investigated.<br/><br>
<br/><br>
Shrinkage behaviour and volume fractions of solid, liquid and gas in kraft and CTMP sheets have been measured using the mercury displacement technique. The gas volume fraction increases continuously with decreasing moisture ratio. Influence of basis weight, pressing and beating was also investigated.<br/><br>
<br/><br>
A triangular phase diagram was developed in which the phase development and shrinkage behaviour of paper can be studied. Analysis showed that kraft sheets shrink continuously in the moisture ranges investigated, while highly refined CTMP sheets showed a region with no shrinkage. Analysis and modelling of the shrinkage behaviour showed that the shrinkage is higher than ideal shrinkage for moisture ratios below approximately 1.0 kg water/kg DS.}},
  author       = {{Baggerud, Erik}},
  isbn         = {{91-7422-042-X}},
  keywords     = {{solid-based coordinates; paper; porous medium; convection; diffusion; volume fractions; mercury displacement; shrinkage; simulations; convective; hot surface; Modelling; drying; Wood; pulp and paper technology; Pappers- och massateknik}},
  language     = {{eng}},
  publisher    = {{Chemical Engineering, Lund University}},
  school       = {{Lund University}},
  title        = {{Modelling of Mass and Heat Transport in Paper - Evaluation of Mechanisms and Shrinkage}},
  year         = {{2004}},
}