A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis
(2020) In Green Chemistry 22(14). p.4450-4455- Abstract
A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is
Please use this url to cite or link to this publication:
https://lup.lub.lu.se/record/bc82e88b-07f6-491d-a5cf-0535ca8fb217
- author
- Pyo, Sang Hyun LU ; Park, Ji Hoon ; Srebny, Vanessa and Hatti-Kaul, Rajni LU
- organization
- publishing date
- 2020
- type
- Contribution to journal
- publication status
- published
- subject
- in
- Green Chemistry
- volume
- 22
- issue
- 14
- pages
- 6 pages
- publisher
- Royal Society of Chemistry
- external identifiers
-
- scopus:85089067921
- ISSN
- 1463-9262
- DOI
- 10.1039/d0gc01454k
- project
- STEPS – Sustainable Plastics and Transition Pathways, Phase 1
- language
- English
- LU publication?
- yes
- id
- bc82e88b-07f6-491d-a5cf-0535ca8fb217
- date added to LUP
- 2020-08-15 13:21:25
- date last changed
- 2022-04-19 00:13:07
@article{bc82e88b-07f6-491d-a5cf-0535ca8fb217, abstract = {{<p>A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is </p>}}, author = {{Pyo, Sang Hyun and Park, Ji Hoon and Srebny, Vanessa and Hatti-Kaul, Rajni}}, issn = {{1463-9262}}, language = {{eng}}, number = {{14}}, pages = {{4450--4455}}, publisher = {{Royal Society of Chemistry}}, series = {{Green Chemistry}}, title = {{A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis}}, url = {{http://dx.doi.org/10.1039/d0gc01454k}}, doi = {{10.1039/d0gc01454k}}, volume = {{22}}, year = {{2020}}, }