2D Ruddlesden-Popper Perovskites for Optoelectronics
(2018) In Advanced Materials 30(2). p.1703487-1703487- Abstract
Conventional 3D organic-inorganic halide perovskites have recently undergone unprecedented rapid development. Yet, their inherent instabilities over moisture, light, and heat remain a crucial challenge prior to the realization of commercialization. By contrast, the emerging 2D Ruddlesden-Popper-type perovskites have recently attracted increasing attention owing to their great environmental stability. However, the research of 2D perovskites is just in their infancy. In comparison to 3D analogues, they are natural quantum wells with a much larger exciton binding energy. Moreover, their inner structural, dielectric, optical, and excitonic properties remain to be largely explored, limiting further applications. This review begins with an... (More)
Conventional 3D organic-inorganic halide perovskites have recently undergone unprecedented rapid development. Yet, their inherent instabilities over moisture, light, and heat remain a crucial challenge prior to the realization of commercialization. By contrast, the emerging 2D Ruddlesden-Popper-type perovskites have recently attracted increasing attention owing to their great environmental stability. However, the research of 2D perovskites is just in their infancy. In comparison to 3D analogues, they are natural quantum wells with a much larger exciton binding energy. Moreover, their inner structural, dielectric, optical, and excitonic properties remain to be largely explored, limiting further applications. This review begins with an introduction to 2D perovskites, along with a detailed comparison to 3D counterparts. Then, a discussion of the organic spacer cation engineering of 2D perovskites is presented. Next, quasi-2D perovskites that fall between 3D and 2D perovskites are reviewed and compared. The unique excitonic properties, electron-phonon coupling, and polarons of 2D perovskites are then be revealed. A range of their (opto)electronic applications is highlighted in each section. Finally, a summary is given, and the strategies toward structural design, growth control, and photophysics studies of 2D perovskites for high-performance electronic devices are rationalized.
(Less)
- author
- Chen, Yani ; Sun, Yong-Hui ; Peng, Jiajun ; Tang, Junhui ; Zheng, Kaibo LU and Liang, Ziqi
- organization
- publishing date
- 2018-01
- type
- Contribution to journal
- publication status
- published
- subject
- keywords
- 2D perovskites, Charge transport, Molecular structures, Optoelectronics, Ruddlesden-Popper
- in
- Advanced Materials
- volume
- 30
- issue
- 2
- pages
- 1703487 - 1703487
- publisher
- John Wiley & Sons Inc.
- external identifiers
-
- scopus:85031322215
- pmid:29028138
- ISSN
- 0935-9648
- DOI
- 10.1002/adma.201703487
- language
- English
- LU publication?
- yes
- id
- be56a41e-ad17-4ac8-9970-c14fc3f7d126
- date added to LUP
- 2017-10-30 09:18:23
- date last changed
- 2024-07-23 06:40:50
@article{be56a41e-ad17-4ac8-9970-c14fc3f7d126,
abstract = {{<p>Conventional 3D organic-inorganic halide perovskites have recently undergone unprecedented rapid development. Yet, their inherent instabilities over moisture, light, and heat remain a crucial challenge prior to the realization of commercialization. By contrast, the emerging 2D Ruddlesden-Popper-type perovskites have recently attracted increasing attention owing to their great environmental stability. However, the research of 2D perovskites is just in their infancy. In comparison to 3D analogues, they are natural quantum wells with a much larger exciton binding energy. Moreover, their inner structural, dielectric, optical, and excitonic properties remain to be largely explored, limiting further applications. This review begins with an introduction to 2D perovskites, along with a detailed comparison to 3D counterparts. Then, a discussion of the organic spacer cation engineering of 2D perovskites is presented. Next, quasi-2D perovskites that fall between 3D and 2D perovskites are reviewed and compared. The unique excitonic properties, electron-phonon coupling, and polarons of 2D perovskites are then be revealed. A range of their (opto)electronic applications is highlighted in each section. Finally, a summary is given, and the strategies toward structural design, growth control, and photophysics studies of 2D perovskites for high-performance electronic devices are rationalized.</p>}},
author = {{Chen, Yani and Sun, Yong-Hui and Peng, Jiajun and Tang, Junhui and Zheng, Kaibo and Liang, Ziqi}},
issn = {{0935-9648}},
keywords = {{2D perovskites; Charge transport; Molecular structures; Optoelectronics; Ruddlesden-Popper}},
language = {{eng}},
number = {{2}},
pages = {{1703487--1703487}},
publisher = {{John Wiley & Sons Inc.}},
series = {{Advanced Materials}},
title = {{2D Ruddlesden-Popper Perovskites for Optoelectronics}},
url = {{http://dx.doi.org/10.1002/adma.201703487}},
doi = {{10.1002/adma.201703487}},
volume = {{30}},
year = {{2018}},
}