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Waste Ochre for Control of Phosphates and Sulfides in Digesters at Wastewater Treatment Plants with Enhanced Biological Phosphorus Removal

Öfverström, Svetlana ; Davidsson, Åsa LU orcid ; Haghighatafshar, Salar LU orcid ; Kjerstadius, Hamse LU and la Cour Jansen, Jes LU (2020) In Clean Technologies 2(1). p.116-116
Abstract
Ochre, waste iron sludge from the treatment of iron rich groundwater for potable use, makes up a significant waste problem. Furthermore, wastewater treatment plants with enhanced biological phosphorus removal and the digestion of sludge are in lack of iron for the prevention of hydrogen sulfide production and the release of phosphorous during anaerobic digestion. Thus, the addition of ochre to anaerobic digestion is a potential beneficial reuse of ochre. Sludge from wastewater treatment plants with enhanced biological phosphorus removal was used for the experiments. Batch and continuous pilot-scale tests were performed for the mesophilic digestion of primary and waste-activated sludge with different doses of ochre. Two different doses of... (More)
Ochre, waste iron sludge from the treatment of iron rich groundwater for potable use, makes up a significant waste problem. Furthermore, wastewater treatment plants with enhanced biological phosphorus removal and the digestion of sludge are in lack of iron for the prevention of hydrogen sulfide production and the release of phosphorous during anaerobic digestion. Thus, the addition of ochre to anaerobic digestion is a potential beneficial reuse of ochre. Sludge from wastewater treatment plants with enhanced biological phosphorus removal was used for the experiments. Batch and continuous pilot-scale tests were performed for the mesophilic digestion of primary and waste-activated sludge with different doses of ochre. Two different doses of ochre corresponding to molar ratios of 1 and 2 moles Fe 3+ /mole P released in the batch test resulted in 29% and 57% reductions of phosphates respectively in the sludge liquor compared to the control sludge without inhibiting the digestion process. In the pilot experiment, the dosing of ochre at both a high and low dose (molar ratios of 1.6 and 0.8 Fe 3+ /S 2− , respectively) resulted in an immediate drop in the H2S concentration (from >2000 ppm down to 570 ppm), while the control reactor still produced biogas with a high hydrogen sulfide concentration. The inhibition of the digestion process was observed (accumulation of acetate) at the higher dose. In a second pilot scale experiment, lower doses of ochre were tested continuously (1.5 and 0.75 mole Fe 3+ /mole Preleased) to avoid any inhibition, while evaluating the phosphate precipitation. A reduction of phosphates in sludge liquor (33% and 66% for the low and high doses respectively) was obtained. (Less)
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author
; ; ; and
organization
publishing date
type
Contribution to journal
publication status
published
subject
keywords
waste ochre, biogas, enhanced phosphorus removal, hydrogen sulfide, phosphates precipitation
in
Clean Technologies
volume
2
issue
1
pages
126 pages
publisher
MDPI AG
external identifiers
  • scopus:85128083173
ISSN
2571-8797
DOI
10.3390/cleantechnol2010008
language
English
LU publication?
yes
id
c0f3e844-f935-497c-8d8d-a611bf6ee3a7
date added to LUP
2020-03-06 16:19:47
date last changed
2023-11-22 15:27:20
@article{c0f3e844-f935-497c-8d8d-a611bf6ee3a7,
  abstract     = {{Ochre, waste iron sludge from the treatment of iron rich groundwater for potable use, makes up a significant waste problem. Furthermore, wastewater treatment plants with enhanced biological phosphorus removal and the digestion of sludge are in lack of iron for the prevention of hydrogen sulfide production and the release of phosphorous during anaerobic digestion. Thus, the addition of ochre to anaerobic digestion is a potential beneficial reuse of ochre. Sludge from wastewater treatment plants with enhanced biological phosphorus removal was used for the experiments. Batch and continuous pilot-scale tests were performed for the mesophilic digestion of primary and waste-activated sludge with different doses of ochre. Two different doses of ochre corresponding to molar ratios of 1 and 2 moles Fe 3+ /mole P released in the batch test resulted in 29% and 57% reductions of phosphates respectively in the sludge liquor compared to the control sludge without inhibiting the digestion process. In the pilot experiment, the dosing of ochre at both a high and low dose (molar ratios of 1.6 and 0.8 Fe 3+ /S 2− , respectively) resulted in an immediate drop in the H2S concentration (from >2000 ppm down to 570 ppm), while the control reactor still produced biogas with a high hydrogen sulfide concentration. The inhibition of the digestion process was observed (accumulation of acetate) at the higher dose. In a second pilot scale experiment, lower doses of ochre were tested continuously (1.5 and 0.75 mole Fe 3+ /mole Preleased) to avoid any inhibition, while evaluating the phosphate precipitation. A reduction of phosphates in sludge liquor (33% and 66% for the low and high doses respectively) was obtained.}},
  author       = {{Öfverström, Svetlana and Davidsson, Åsa and Haghighatafshar, Salar and Kjerstadius, Hamse and la Cour Jansen, Jes}},
  issn         = {{2571-8797}},
  keywords     = {{waste ochre; biogas; enhanced phosphorus removal; hydrogen sulfide; phosphates precipitation}},
  language     = {{eng}},
  month        = {{03}},
  number       = {{1}},
  pages        = {{116--116}},
  publisher    = {{MDPI AG}},
  series       = {{Clean Technologies}},
  title        = {{Waste Ochre for Control of Phosphates and Sulfides in Digesters at Wastewater Treatment Plants with Enhanced Biological Phosphorus Removal}},
  url          = {{https://lup.lub.lu.se/search/files/77009376/cleantechnol_02_00008_v2.pdf}},
  doi          = {{10.3390/cleantechnol2010008}},
  volume       = {{2}},
  year         = {{2020}},
}